GCMS calibration analysis results, DEP Labs, Feb 2002

NYC 9/11 Public Portal Document

Library Search Compound Report ' ’Data File : C:\MSDCHEM\l\5973N\02FEB21\0123B.D Vial: 1 Acq On : 21 Feb 2002 10:46 am Operator: Sample : lab blank 1/23 Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l..-\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 3 Pyrrolidine, 1-methyl- Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

4.65 0.04 ug/L 16497 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Pyrrolidine, 1-methyl- 85 C5H11N 000120-94-5 9 2 Acetyl valeryl $$ 2,3-Heptanedio. .. 128 C7H12O2 000096-04-8 9 3 Pentane, 2,2-dimethyl- 100 C7H16 000590-35-2 9 4 Cyclopropanecarboxylic acid $$ C... 86 C4H602 001759-53-1 7 Abundance Scan 113 (4.649 min): 0123B.D (-) m/z 88.00 100.00% 88 A 57 41 5000

4.40 4.60 4.80 5.00 0 i । i । । * j i > * • । < rump * ■ ■ ■ ■ i ■1 ■ ■) ■ ■ ■ • i • • ■ ■ i 1 ■ j m/z 57.10 73.17% mfe-> 20 30 40i 50 60 70 80 90 100 110 120 130 Abundance #3657: Pyrrolidine, 1-methyl- 42 57 84

5000- 4.40 4.60 4.80 5.00 m/z 41.10 60.22% 27 O—T ■ I ■ ■ ■ ■ i 1 । i I ' I1! 1 ■ i ■ ■ ■ 1 i ■ • ■ ■ i ■ ■ ■ ■ i ■ • ■ • i ‘ 1

miz-> 20 30 40 50 60 90 70 100 110 120 80 130 Abundance #24363: Acetyl valeryl $$ 2,3-Heptanedione (CAS) $$ Valery... 43 57 ■ i ■ ■ ■ ■ i —ImmTT 4.40 4.60 4.80 5.00 29 5000 m/z 85.00 36.69% 85

O—TTT —Hi - ■ । 160. p 1 ' i ' ■ ' ■ i ■' ■ ■ i ■ ‘ ■ i ■ ■ 128 ■1 i ■ ■

mtz—> 20 30 40I 50 70 80 90 100 110 120 130 Abundance #8707: Pentane, 2,2-dimethyl- ■ ■ i ■ 1 1 1 1 1 1 1 57 4.40 4.60 4.80 5.00 m/z 56.10 26.26% 43 5000 85

m/z-> O—TT 20 27 IP30 40 111Br 50 + ' 90 100‘‘10‘ 120‘‘130 60 70 80 4.40 4.60 4.80 5.00

0123B.D HP022102.M Mon Feb 25 10:54:36 2002 Page 5

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