GCMS calibration analysis results, DEP Labs, Feb 2002

NYC 9/11 Public Portal Document

Library Search Compound Report ■ ’Data File : C:\MSDCHEM\l\5973N\02FEB21\0123B.D Vial: 1 Acq On : 21 Feb 2002 10:46 am Operator: Sample : lab blank 1/23 Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\HP022102 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 4 3-(CYCLOHEX-3'-EN-YL)PROPAN... Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

5.95 0.33 ug/L 144435 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ ... 174 C8H14O4 015745-87-6 38 2 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 38 3 Acetamide, N-methyl- (CAS) $$ N-... 73 C3H7NO 000079-16-3 9 4 Acetamide, N-methyl-73 C3H7NO 000079-16-3 9 Abundance Scan 228 (5.948 min): 0123B.D (-) m/ z 73.10 100.00% 73

5000- 43 ■ ■ i ■ • ■ ■ i ■ ■ • ■ । ■ AOOOa ■ ■ ■ । • 5.60 5.80 6.00 6.20 _1 1, ...55 i..... i,i, i 87 103 m/z 43.10 24.82% O'- !■ ■■ 'I ■ 1111′1 11' '“i' ■1111 —mpmTP miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138:3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1 -p... 73 _........ . A 5000 ’ ‘ ‘ H 5.60 5.80 6.00 6.20 43 m/z 41.10 10.06% 27 55 ,i , 87 174 113 11' “11rT'111 r" i111' i" " 11 0-mmm 1 1 * * 1 ' “ 1 1 ■ ■ i “1 ■ i " “ 1" " 1 '" i1 mfe-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73 ■ ■ i ■ ■ ■ ■ i 1 5.60 A 5.80 6.00 6.20 5000 m/z 45.00 8.24% 43 27 87 0 Pt 55 ■ I ■ i • “' i ■' ■ ■ T' Hpn i' ‘" i■ i 113 174 ■ i" ' 'I “ “ I ■ ■ ■ ■ i ■ ■ ■ ■ i “ '' i ‘1 ■ ■ i' iz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #1786: Acetamide, N-methyi- (CAS) $$ N-Methylacetamide $$... - ■ i ■ - - - i ■ - - ■ i - - ' 1 1 ' 1 - - i - 30 43 73 5.60 5.80 6.00 6.20 m/z 71.00 5.64% 5000 58 15

0 TPPput lhajani ’i “ " i -' “ i - - - -1 - - - -1 - - “ i - -" i - - - -1 “ - -1 - - - -1 - - - -1 - “ ■ i" " i - ' ‘ I ‘ ‘ ' I ‘ ‘ ‘ ‘ 1 1 1 1 1 I 1 1 1 1 I 1 m/z-> 10 . 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20

0123B.D HP022102.M Mon Feb 25 10:54:37 2002 Page 6

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