GCMS calibration analysis results, DEP Labs, Feb 2002

NYC 9/11 Public Portal Document

Library Search Compound Report • • Data File : C:\MSDCHEM\l\5973N\02FEB21\0123B.D Vial: 1 Acq On : 21 Feb 2002 10:46 am Operator: Sample : lab blank 1/23 Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1... \HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 5 Acetamide, 2-cyano- (CAS) $... Concentration Rank 8 R.T. EstConc Area Relative to I STD R.T. 8.05 0.04 ug/L 16411 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetamide, 2-cyano- (CAS) $$ Cya... 84 C3H4N20 000107-91-5 4 2 2-Butynoic acid $$ Tetrolic acid... 84 C4H402 000590-93-2 4 3 PROPENE-1,1-D2 44 C3H4D2 001517-49-3 4 4 Acetamide, 2-cyano- 84 C3H4N20 000107-91-5 4 Abundance Scan 414 (8.047 min): 0123B.D (-) m/ z 43.10 100.00% 43

5000- 49 84 7.80 8.00 8.20 8.40 01 “ i “ ■ ■ i" “ i “ “ i “ • ‘ i ■" • i ■ ■' ‘ i ■ “ • i ■ ■ 1i8 i “ ■ ■ i ■1 ■ ■ i' • ■ ‘ i ■' “ i “ " i I'"1!1'".......I m/z 44.00 70.60% miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3100: Acetamide, 2-cyano- (CAS) $$ Cyanacetamide $$ Cyano... 44 41

5000 7.80 8.00 8.20 8.40 m/z 49.05 27.59%

miz-> Abundance 1316 L 27 68 H1 tmmmmmmmmmmmmmmmm 01 " i" ■' i" i1'" i" " 111" i “ 38 84 ■ 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 93 #3130:2-Butynoic acid $$ Tetrolic acid $$ 1-Propynecarbox... MWWwwMN 39 44

7.80 8.00 8.20 8.40 5000 m/z 83.90 7.47%

mH ol 12 16 TOmmpupm 25 36 67 84 WWWMMMMlpmN miz-> Abundance 5 11 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 #173: PROPENE-1.1-D2 43 7.80 8.00 8.20 8.40 m/z 85.95 2.41% 5000

27 40 w 16 46 30 37

miz-> -hull T*u-puTIWTuPgi Ol •»t * * • • i • • 11 * * > i * • T’IT’I 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 7.80 8.00 8.20 8.40

0123B.D HP022102.M Mon Feb 25 10:54:37 2002 Page 7

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