GCMS blank analysis report for sample AE02713, March 4 2002

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.. Data File : C:\MSDCHEM\1\5973N\02FEB28\0205B.D Vial: 1 Acq On : 28 Feb 2002 10:30 am Operator: Sample : lab blank 2/5 Inst : Instrumen Mise : February 2 8, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 5 3-(CYCLOHEX-3'-EN-YL)PROPAN... Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 5.94 0.35 ug/L 143003 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 33 2 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 33 3 1-Propene-l-thiol 74 C3H6S 000925-89-3 9 4 N-Ethylformamide $$ N-Formylethy... 73 C3H7NO 000627-45-2 9 Abundance Scan 227 (5.936 min): 0205B.D (-) m/ z 73.10 100.00% 73

5000 43 ■ ■ i ■ ■ ■ ■ i ■ ■ Tdd 5.60 5.80 6.00 6.20 ...... ........ . ", • ■ i ■ •87 i 103 0- 111111111■ > 1’4 11.।. 11* ■ i ■'• • • i ‘ “ i • •' ■ i • • ■ • i ■' " i •' ■ ■ i " ■ ■ i" " i • m/z 43.10 26.13% z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138:3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 73

5000 ■ ■ i ■ ■ TT’ r. , । । । 5.60 5.80 6.00 6.20 43 m/z 45.10 10.85% 27 55 . , 87 113 174 i 0-1B222’ 13TP 1u—1———]——unmmummmup niz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73 TI 5.60 5.80 6.00 6.20 5000 m/z 41.10 10.08% 43 27 55 , , 87 113 174 0 11 “ “ i' TTTp —————— nz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #2002:1-Propene-1-thiol • i * • * • i 73 5.60 5.80 6.00 6.20 m/z 71.00 7.29% 5000 43

1, i■ ■57,'I'i“f>. I•. *.।।1।।।।।।।।. o1 ■ i■"■ i■ ■ “iTta ■ ‘ i ‘ ‘ • i ‘ ‘ ' 1 r■ ' ■ ‘ i ' ■ ' ‘ i m/z—> 2030405060 70 8090 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20

0205B.D HP022102.M Fri Mar 01 10:06:45 2002 Page 7

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