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GCMS analysis results for sample AE10816, May 2002

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Laboratory report showing GC/MS analysis results for sample AE10816 including surrogate recovery data on May 14, 2002.

NYC-WTC_000023502–000023516

Folder label: “GCMS X 5/9/02 A 5/13/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\051302\10816.D Vial: 13 Acq On : 13 May 2002 9:16 pm Operator: Mclean Sample : 5/9 kb Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHCDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 2 Pyrrolidine, 3-methyl- Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 3.75 0.26 ug/L 239767 1,4-Dichlorobenzene-d4 9.94 Hit# Of 5 Tentative ID MW MolForm CAS# Qual 1 Pyrrolidine, 3-methyl- 85 C5H11N 034375-89-8 5/ 2 4-Penten-2-one 84 C5H80 013891-87-74 3 3-Oxobutyric acid, 2-chloroethyl... 164 C6H9C1O3 1000210-13-3 4 4 Furan, 2,3-dihydro-5-methyl- 84 C5H8O 001487-15-6 3 Abundance Scan 114 (3.749 min): 10816.D (-104) (-) m/z 43.10 00.00% 40

5000 waAWWAw ■ ■ i ■ ■ ■ ' i ' ■ 1 ' i ■ • ■ • i ■ 35 3.40 3.60 3.80 4.00 51 63 85 L. I -mm*mm*******mmm*mmmmmmmmmmmmmmmmmmPm 01 ’1’’11111117111111 m/ z 47.00 9.99% m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #7036: Pyrrolidine, 3-methyl- 43 wMlolatnottnu 5000 v 3.40 3.60 3.80 4.00 28 85 m/Z 85.00 9.21%

miz-> 01 "II- 15 i + 56 68 ye --- ।, 93.................................................. 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #109203:4-Penten-2-one 43 A / W A , AA A ,, A A 3.40 . 3,60 3.80 4.00 5000 m/z 50.00 8.75%

0 28 84 I. ----- I J m/z-> Abundance 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170

43 #7067: 3-Oxobutyric acid, 2-chloroethyl ester 11/117114/111/1/4/171471I 3.40 3.60 3.80 4.00 111/8

m/Z 83.90 8.59% 5000 "WopirialVtolwhwo_a,a, 63 85

m/z-> 0 --HPl I, ,73 ,|, 93 102 115 124 136 149 164 ri 1 r11111 i'i 1111 Il’i 11111111111 > >'i 11111111111111111111111111111 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 3.40 3.60 3.80 4.00

10816.D 050102.M Tue May 14 11:42:56 2002 Page 5

NYC-WTC_00002351 1

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NYC-WTC_000023511Source: NYC Law Department, mirrored locally

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