GCMS surrogate recovery report, sample AE12763, June 2002

NYC 9/11 Public Portal Document Library Search Compound. Report Data File : C:\MSDCHEM\l\DATA\061102\12763.D Vial: 7 Acq On : 11 Jun 2002 2:46 pm Operator: Sample : re-ext. Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library- : C:\DATABASE\NIST98.L Peak Number 7 1-Pyrrolidineethanamine Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. 3.97 1.30 ug/L 1062230 1,4-dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1- Pyrrol idineethanamine 114 C6H14N2 007154-73-6 4 2 2-Piperidinecarboxylic acid 129 C6H11NO2 000535-75-1 4 3 Prolin, N-methyl-, butyl ester 185 C10H19NO2 1000152-96-3 2 4 2-Piperidinecarboxylic acid, (. + ... 129 C6H11NO2 004043-87-2 2 Abundance / Scan 152 (3.972 min): 12763.D (-149) (-) m/z 49.10 100.00% 49 84

5000-

35 58 3 60 3.80 4.00 4.20 4.40

z-> 0. l11" I ’ ‘I H TTTT m 10 20 30 40 50 60 70 80 90 100110120130 140150160170 180 190 *0-2-1—0111111111115311111012111333011537171’1’3 m/z .84.00 89.16% Abundance #33571:1-Pyrrolidineethanamine 84

42 5000 360 3.80 4.00 4.20 4.40 55 m/z 48.10 62.95% 30

mfe-> ..... .. 0- rirj 1*7’11+1’4

Abundance 70 111t-2n1——TRTaauuT -++ll 96 111 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 #33693:2-Piperidinecarboxylic acid /wd 84 3 60 3.80 4.00 4.20 4.40 5000 m/z 58.00 23.34% 56

41 । 67 ---+--+74mttl । 100 112 129 0 । । ।■ i'" ■ I" " । " i1,1111111111" i"111" m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #33580: Prolin, N-methyl-, butyl ester 84 3.60 3.80 4.00 4.20 4.40 m/z 35.10 17.92% 5000 42

55 — /MMNus, 0 mmMH - 1 67 100 110 128 144 156 185 i ““ l'“ ■ i" “ i“ ■11 ‘ " i ■1 “ i"" 11111111 “ I"'" I “ n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 3.60 3.80 4.00 4.20 4.40

12763.D 060302.M Tue Jun 11 15:54:00 2002 Page 10

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