GCMS reference standard analysis, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\MAR3002\REFAl.D Vial: 27 Acq On : 30 Mar 2002 6:45 pm Operator: Sample : gc/ms scan 3/8 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Mar 30 19:33 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 29 10:31:28 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.25 152 483787 20.00 ug/1 -0.10 10) Naphthalene-d8 15.89 136 1766209 20.00 ug/1 -0.11 17) Acenaphthene-dlO 21.20 164 998276 20.00 ug/1 -0.12 29) Phenanthrene-dlO 25.64 188 1444318 20.00 ug/1 -0.13 38) Chrysene-dl2 33.70 240 793057 20.00 ug/1 - 0.1.4 44) Perylene-dl2 37.94 264 451511 20.00 ug/1 -0.18

System Monitoring Compounds if. 37) 2,4-DDD 30.72 235 88831- ug/mL 0.22 Spiked Amount 5.000 Recovery

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.89 74 86116 5.25 ug/1 # 66 3) bis(2-Chroroethyl)ether 11.64 93 214828 .8.13 ug/1 91 4) 1,3-Dichlorobenzene 12.14 146 170517 6.24 ug/1 98 5) 1,4-Dichlorobenzene 12.29 146 177639 6.49 ug/1 100 6) 1,2-Dichlorobenzene 12.81 146 177903 6.97 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 13.13 45 298094 .8.01 ug/1 98 8) N-Nitroso-di-n-propylamine 13.51 70 140202 8.15 ug/1 # 86 9) Hexachloroethane 13.66 117 53629 5.24 ug/1 100 11) Nitrobenzene 13.93 77 195709 8.11 ug/1 91 12) Isophorone 14.58 82 428715 9.36 ug/1 99 13) bis(2-Chloroethoxy)methane 15.26 93 261108 8.71 ug/1 96 14) 1,2,4-Trichlorobenzene 15.77 180 157080 7.58 ug/1 97 15) Naphthalene 15.94 128 574515 8.80 ug/1 99 16) Hexachlorobutadiene 16.49 225 62031 6.00 ug/1 99 18) Hexachlorocyclopentadiene 18.68 237 19227 2.84 ug/1 98 19) 2-Ghloronaphthalene 19.45 162 353346 8.24 ug/1 95 20) Dimethylphthalate 20.53 163 488190 9.72 ug/1. 99- 21) 2,6-Dinitrotoluene 20.76 165 99178 8.13 ug/1 # 80 22) Acenaphthylene 20.72 152 535564 8.74 ug/1 99 23) Acenaphthene 21.29 153 378706 8.84 ug/1 99 24) 2,4-Dinitrotoluene 21.92 165 126613 7.76 ug/1 # 75 25) Diethylphthalate 22.67 149 463505 9.50 ug/1 # 94 26) 4-Chlorophenyl-phenylether 22.83 204 203796 9.76 ug/1 90 27) Fluorene 22.80 166 423978 9.36 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.29 77 397696 7.61 ug/L # 85

{#) = qualifier out of range (m) = manual integration REFAl.D GCMS0308.M Tue Apr 02 15:13:03 2002 Page 1

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