GCMS Method 525.2 reference standard results, Mar 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\MAR2702\REF2.D Vial: 5 Acq On : 27 Mar 2002 5:37 pm Operator: Sample : gc/ms scan 3/2 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Mar 29 12:36 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 29 10:31:28 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.25 152 740182 20.00 ug/1 -0.10 10) Naphthalene-d8 15.89 136 2881899 20.00 ug/1 -0.11 17) Acenaphthene-dlO 21.20 164 1556950 20.00 ug/1 -0.12 29) Phenanthrene-dlO 25.65 188 2271366 20.00 ug/1 -0.12 38) Chrysene-dl2 33.71 240 1234032 20.00 ug/1 -0.14 44) Perylene-dl2 37.95 264 681889 20.00 ug/1 -0.17

System Monitoring Compounds 37) 2,4-DDD 30.72 235 81725 3.59 ug/mL 0.22 Spiked Amount 5.000 Recovery = 71.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.88 74 85288 3.40 ug/1 # 72 3) bis(2-Chloroethyl)ether 11.65 93 194616 4.81 ug/1 89 4) 1,3-Dichlorobenzene 12.15 146 159717 3.82 ug/1 96 5) 1,4-Dichlorobenzene 12.29 146 168108 4.01 ug/1 99 6) 1,2-Dichlorobenzene 12.81 146 166864 4.27 ug/1 98 7) 2,2'-oxybis(1-Chloropropan 13.13 45 273926 4.81 ug/1 98 8) N-Nitroso-di-n-propylamine 13.51 70 136171 5.18 ug/1 # 86 9) Hexachloroethane 13.66 117 48899 3.12 ug/1 99 11) Nitrobenzene 13.93 77 179611 4.56 ug/1 91 12) Isophorone 14.58 82 407216 5.45 ug/1 100 13) bis(2-Chloroethoxy)methane 15.26 93 243065 4.97 ug/1 98 14) 1,2,4-Trichlorobenzene 15.77 180 149466 4.42 ug/1 95 15) Naphthalene 15.94 128 532580 5.00 ug/1 99 16) Hexachlorobutadiene 16.49 225 53411 3.17 ug/1 98 18) Hexachlorocyclopentadiene 18.68 237 23213 2.20 ug/1 96 19) 2-Chloronaphthalene 19.45 162 332006 4.97 ug/1 95 20) Dimethylphthalate 20.53 163 451982 5.77 ug/1 99 21) 2,6-Dinitrotoluene 20.76 165 92202 4.85 ug/1 # 82 22) Acenaphthylene 20.72 152 517071 5..41 ug/1 99 23) Acenaphthene 21.29 153 355078 5.32 ug/1 99 24) 2,4-Dinitrotoluene 21.92 165 114873 4.51 ug/1 # 77 25) Diethylphthalate 22.67 149 428221 5.63 ug/1 95 26) 4-Chlorophenyl-phenylether 22.83 204 194130 5.96 ug/1 90 27) Fluorene 22.80 166 397869 5.63 ug/1 98 2 8) Azobenzen/ 1,2-Diphenylhyd 23.29 77 365894 4.49 ug/L # 84

(#) = qualifier out of range (m) = manual integration REF2.D GCMS0308.M Fri Mar 29 12:37:21 2002 Page 1

NYC-WTC_000058180