GCMS calibration results, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed),

Data File : C:\HPCHEM\l\DATA\MAR3002\REF.D •Vial: 5 Acq On : 29 Mar 2002 6:55 pm Operator: Sample : gc/ms scan 3/6 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 2 10:39 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 29 10:31:28 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.25 152 503821 20.00 ug/1 -0.10 10) Naphthalene-d8 15.89 136 1825420 20.00 ug/1 -0.11 17) Acenaphthene-dlO 21.19 164 1015386 20.00 ug/1 -0.12 29) Phenanthrene-dlO 25.64 188 1467741 20.00 ug/1 -0.13 . 38) Chrysene-dl2 33.70 240 807925 20.00 ug/1 -0.15 44) Perylene-dl2 37.94 264 436319 20.00 ug/1 -0.18

System Monitoring Compounds 37) 2,4-DDD 30.71 235 78548 5.33 ug/mL 0.22 Spiked Amount 5.000 Recovery = 106.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.89 74 89721 5.25 ug/1 # 72 3) bis(2-Chloroethyl)ether 11.65 93 210783 7.66 ug/1 88 4) 1,3-Dichlorobenzene 12.15 146 147520 5.19 ug/1 98 5) 1,4-Dichlorobenzene 12.30 146 158480 5.56 ug/1 98 6) 1,2-Dichlorobenzene 12.81 146 161255 6.06 ug/1 100 7) 2,2'-oxybis(1-Chloropropan 13.13 45 292470 7.55 ug/1 99 8) N-Nitroso-di-n-propylamine 13.52 70 141292 7.89 ug/1 # 84 9) Hexachloroethane 13.66 117 34294 3.22 ug/1 98 11) Nitrobenzene 13.93 77 190317 7.63 ug/1 92 12) Isophorone 14.58 82 418145 8.84 ug/1 99 13) bis(2-Chloroethoxy)methane 15.26 93 257491 8.31 ug/1 98 14) 1,2,4-Trichlorobenzene 15.77 180 142737 6.66 ug/1 97 15) Naphthalene 15.94 128 539783 8.00 ug/1 99 16) Hexachlorbbutadiene 16.49 225 25973 2.43 ug/1 99 18) Hexachlorocyclopentadiene 18.68 237 12226 1.78 ug/1 96 19) 2-Chloronaphthalene 19.45 162 330539 7.58 ug/l 95 20) Dimethylphthalate 20.53 163 463813 9.08 ug/1 99 21) 2,6-Dinitrotoluene 20.75 165 96060 7.74 ug/1 # 80 22) Acenaphthylene 20.72 152 527682 8.47 ug/1 99 23) Acenaphthene 21.29 . 153 361308 8.29 ug/1 98 24) 2,4-Dinitrotoluene 21.92 165 119405 7.20 ug/1 # 77 25) Diethylphthalate 22.67 149 446998 9.01 ug/1 96 26) 4-Chlorophenyl-phenylether 22.83 204 191039 8.99 ug/1 .90 27) Fluorene 22.80 166 401546 8.72 ug/1 99 28) Azobenzen/ 1,2-Diphenylhyd 23.29 77 375690 7.07 ug/L # 85

(#) = qualifier out of range (m) = manual integration REF.D GCMS0308.M Tue Apr 02 10:42:10 2002 Page 1

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