GCMS analysis results for sample AE00838, Feb 4 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02JAN31\00838.D Vial: 2 Acq On : 31 Jan 2002 3 :32 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 31, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l..-\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 12 4-METHOXY-.BETA.-METHYLCINN. . . Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 22.28 0.17 ug/L 143734 Phenanthrene-dl0 22.65 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 72 2 Phenanthrene, 9-methyl- $$ 9-Met... 192 C15H12 000883-20-5 59 3 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 42 4 N-perdeuteriobenzylideneaniline 192 C13D11N 000538-51-2 42 Abundance Scan 1656 (22.280 min): 00838.D (-) m/z 192.10 100.00% 192

5000 ......................................... .. 82 96 146 40 22.00 22.20 22.40 22.60 42 54 70 । 118 135 | 160 01 1111 • • 11 •1 > r • •11111111 * >1 TTHT TPITPTTT , |, m/z 191.10 17.25% ‘111 m/z-> Abundance 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 #102588:4-METHOXY-BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192 N 108 5000 I ′ ' ' 22.00 22.20 22.40 22.60 146 175 m/ Z 146.10 15.66% / n/z-> 0 • i ■1 ■ ■ i ■r" 11 ‘■ i ’ ■ ■ ■ i • I'''' I 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 ■ i " ■ ■ i ■ ■ ■ ■ i' ..... U Abundance #103936: Phenanthrene, 9-methyl- $$ 9-Methylphenanthrene 192 21/001101/0/4, — 22.00 22.20 22.40 22.60 5000 m/z96.10 15.14%

88 as 139 152 165 176 . | 001) 1‘10mu00unun—dtm—m‘uuuwumn"um——n—nmadtuannnh 1 ’ 'T /z- > 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103930: Phenanthrene, 2-methyl- 192 22.00 22.20 22.40 22.60 m/z 193.10 14.03%

5000 A 96

m/z-> 0 ....... 881, ■' i " ■ ■ i' 139 152 165 176 + 11ri 111' T-pn ■ i " " 111" 111'111111111 • ■ r ■ ■111 ’ " i " ■ ■ i ■''' i1" ' i ■ 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 + 22.00 22.20 22.40 22.60 T

30838.D SCAN508.M Fri Feb 01 09:19:07 2002 Page 14

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