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GCMS analysis results for sample AE00465, Jan 18 2002

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Laboratory report documenting gas chromatography-mass spectrometry analysis of environmental sample AE00465 conducted on January 18, 2002.

NYC-WTC_000051222–000051235

Folder label: “GCMS X 1/8/02 A 1/10/02

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NYC 9/11 Public Portal Document

Library Search Compound Report . Data File : C:\MSDCHEM\1\5973N\02JAN10\00328.D Vial: 1 Acq On 10 Jan 2002 2:49 pm Operator: Sample : 508 scan ext 1/8 Inst : Instrumen Mise : January 10, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ****************************************************************** *** Peak Number 5 l-amino-2-methyl-4-isopropy... Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 22.28 0.14 ug/L 77200 Phenanthrene-dl0 22.63 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1-amino-2-methyl-4-isopropyl-thi... 192 C5H13N4PS 107264-54-0 50 2 N-(2-methylprop-2-enyl )-2-nitrob... 192 C10H12N2O2 000000-00-0 47 3 1,5-Naphthalenedithiole 192 C10H8S2 000000-00-0 45 4 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 42 Abundance Scan 1656 (22.280 min): 00328.D (-) m/z 192.10 100.00% 192

5000

96 146 160 2200 22.20 22.40 22.60

n/z-> 0- —ITTTTPTT 49 64 82 i ■ ■'11 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 M m/z 96.00 16.98%

Abundance #101918:1 -amino-2-methyl-4-isopropyl-thiotriazaphospholin... 159 192

5000 22.00 22.20 22.40 22.60 144 177 m/z 191.10 15.33% 0 i ""i ""i r1" ■ ।" " । । ■ ■ ■ ■ । ■ • •. । r ■'11'1'' i — 1300111 I— /z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102494: N-(2-methylprop-2-enyl)-2-nftrobenzenamine 192 77 151 130 22.00 22.20 22.40 22.60 93 104 m/z 193.10 5000 13.11% 119

177 0 '11" " i' ‘ " i " " i " 111" "111111 ' " I ' TT’T l’ ’’ V ' i " " i ‘ " 11 " " r ■ " I -rrp-. n/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102434: 1,5-Naphthalenedithiole ’ I’’ ’’I 1 1 ’ ' r1 11 1 1' 1 192 22.00 22.20 22.40 22.60 m/z 146.10 12.74% 5000

115 128 159

147 33 102 . / 0 TP’NTpgtvrri i 11 ।! 11 11 ।, 11 11 । vr 11' r 1’ 111" I' " ' l * " • I ’ ‘ "i""i■• 1’’ I" ' j TTT m/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.00 22.20 22.40 22.60

)0328.D SCAN508.M Fri Jan 11 10:08:22 2002 Page 7

NYC-WTC_000051232

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NYC-WTC_000051232Source: NYC Law Department, mirrored locally

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