GCMS surrogate recovery results for sample AE00282, Jan 2002

NYC 9/11 Public Portal Document Data File : C:\MSDCHEM\1\5973N\02JAN09\282.D Vial: 7 Acq On : 9 Jan 2002 11:12 pm Operator: Sample : 508 scan ext 1/7 Inst : Instrumen Mise : January 9, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L * ********************************************************************* Peak Number 2 2,3,4,5-Tetrahydropyridazine Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T. 4.86 0.18 ug/L 70893 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2,3,4,5-Tetrahydropyridazine 84 C4H8N2 000694-06-4 9 2 Pyridine, 2,3,4,5-tetrahydro- (C... 83 C5H9N 000505-18-0 9 3 2-Pentyn-l-ol 84 C5H80 006261-22-9 9 4 5-Hexenal oxime 113 C6H11NO 057606-82-3 9 Abundance Scan 130 (4,858 min): 282.D (-) m/z 83.95 100.00% 84

5000 39 55 59 A—v '■’T' ' ' ' I L 1 ' I ' TT i Prr

w n/z-> 01 ■ ' I ' ''' I ■' ' 1 I'''' I ' 20 25 30 35 JR 40 44

45 51 TT 50 55 p ' ' ' I ' b '' I ' ‘ 60 65 70 ' I ' ' 75 80 I r' 1 1 I 85 90 m/ z 4.60 4.80 55.10 5.00 5.20 72.24% Abundance #3177: 2,3,4,5-Tetrahydropyridazine 84 29 5000 , .4, 55 41 4.60 4.80 5.00 5.20 26 69 m/ Z 59.00 46.64%

nil. mL. 14 ।

n/z-> ol ■ 111 ■ ■r i 20 25 30 35 40 I45.. 50 55 60 65 70 75 80 ■ i • ■ ■ ■ I ' ■ l' 1 1 1 1 ' r 85 90

M Abundance #3046: Pyridine, 2,3,4,5-tetrahydro- (CAS) $$ Tetrahydropy... 55 - ..... .A, 83 4.60 4.80 5.00 5.20 5000 m/ z 39.10 43.19% 41

0 IITTTIPTTTT I■r(....।I I) 1 51 । 68 80 ' i ■ ■ ■ ■ i '

n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3291: 2-Pentyn-1-ol ■ i ■ ■ ' ' i ' ■ • ' 39 55 4.60 4.80 5.00 5.20 m/z 83.10 38.96% 83 5000 27 44 51 66

n/z-> 0 ■ ■ i ■ ■ ■ ■ i ■ 20 25 mPP 30 35 +44 60 65 70 75 80Pl85.....90 40 45 50 55 — 1 ' I ' 1 ' ' I ' 4.60 4.80 5.00 5.20

82.D SCAN508.M Thu Jan 10 11:52:04 2002 Page 4

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