GCMS analysis results for sample AE03075, March 5 2002

NYC 9/11 Public Portal Document

Library Search Compound Report : Data File : C:\MSDCHEM\l\5973N\02FEB28\02715 .D Vial: 5 Acq On : 28 Feb 2002 1:50 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 28, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 7 2,3,4,5-Tetrahydropyridazine Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

4.87 0.10 ug/L 42035 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2,3,4,5-Tetrahydropyridazine 84 C4H8N2 000694-06-4 64 2 2-Pentenal, (E)- 84 C5H80 001576-87-0 43 3 2-Pentyn-l-ol 84 C5H80 006261-22-9 9 4 (Z)-1-Propenylaziridine $$ Aziri... 83 C5H9N 024461-38-9 7 Abundance Scan 133 (4.875 min): 02715.D (-) m/z 83.95 100.00% 84

5000 41

51 55 NWW w ■ 1 i ■ ■ ' ■ i ■ ■ ■ ■ i ■ ■ ■ 1 i ■ ■ 44 4.60 4.80 5.00 5.20 - r ol ■' i • ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ • ■ ■ i'1 i ■ ■ ■ ■ i ■1 m/ z 55.10 60.29% m/z-> 20253035 40 45 50556065 70 75 808590 Abundance #3177:2,3,4,5-Tetrahydropyridazine 84

29 ■ 5000 55 1 ■ ' ‘ I ‘ ‘ ‘ ‘ I ' ' ‘ ' I ‘ ' I ‘ ‘ '

41 4.60 4.80 5.00 5.20 26 69 m/z 41.10 52.03% 44 Of ■ ■ । ■ ■ ■ ■ । ■ ■ i “ " i i ■ ■ ■ ■ i ■ ■ ■11 ■ ■ ■11 ■ ■ i ■ • •11 “ ■ ■ i ■ ■ -[-m-rp-T m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3201:2-Pentenal, (E)- 55 27 39 84 4.60 4.80 5.00 5.20 5000- m/z 83.0.0 51.03%

51 01 “ i1' “ i 35, TTTTTTT L 66 Tmmmmmt i' “ ■ i • ■ miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3291:2-Pentyn-1-ol 39 55 4.60 4.80 5.00 5.20 m/z 51.00 18.60% 83 V 5000 27 NN A N 44 51 66

miz-> 0i ‘ ■ i ■ ■1 ‘ i ■ 20 25 Trrp-m-p- 30 35 —4 404550556065 mmm 11.1. ’I’" 70 75 8085 90 P 4.60 4.80 5.00 5.20

02715.D HP022102.M Fri Mar 01 10:07:07 2002 Page 9

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