GCMS analysis results, sample AE02719, March 2002

NYC 9/11 Public Portal Document

Library Search Compound Report •* Data File : C:\MSDCHEM\1\5973N\02FEB28\02719.D Vial: 4 Acq On : 28 Feb 2002 5:10 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 2 8, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 6 2,3,4,5-Tetrahydropyridazine Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 4.90 0.04 ug/L 14499 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2,3,4,5-Tetrahydropyridazine 84 C4H8N2 000694-06-4 56 2 1-ETHOXYPROPA-1,2-DIENE $$ 1,2-P... 84 C5H80 013077-71-9 5 3 3,4-Dideuterio-l-methylpyrazole 84 C4H4D2N2 000000-00-0 4 4 (E)-1-Propenylaziridine $$ Aziri... 83 C5H9N 080839-91-4 4 Abundance Scan 135 (4.898 min): 02719.D (-) m/z 83.95 100.00% 84

55 5000 51 -Waus 41 ■ ■ • i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ • ■ i ■ ■ • 1 4.60 4.80 5.00 5.20 01 ■ ‘ i ■ ‘ ' i ■ ■ ‘ ■ i ■ • ■ ■ i ‘ ■ i11 ‘ i • ■ • • i ■ • i ■ • ■ ■ i' ■ ■' i •1' • i ■1 ‘ ‘ 11 ■ i ■ “ • i ‘ ‘ m/z 55.10 56.33% m/z-> 2025303540 45 50556065 70 75 808590 Abundance #3177:2,3,4,5-Tetrahydropyridazine 84

29 5000 55 ' ' II !■> 1 । | I l' l »'|"l ■ I I | 1 I I I

41 4.60 4.80 5.00 5.20 26 69 m/z 83.00 46.55% 44 0+ ■ ■ i ■ ■ ■ ■ i ■ • i ■ ■ ■ ■ i I ■1 ■ ■ i' ■ '■i■1 ■ ■ i ■■ ’’**1** niz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3341:1-ETHOXYPROPA-1.2-D1ENE $$1,2-Propadiene, 1-ethoxy... $ ■ ■ i ■ ■ ■ ■ i ■ ■ < i * ■ • ■ i • ■ 4.60 4.80 5.00 5.20 5000 m/z 51.00 35.77% 27 39 84 N miz-> 01 -n-p-n-rp- ' ■ i1 ■ ■ ■ i' ■ i1 ■'1 p 1 ■ ■ i ■ ■ 20 25 30 35 40 45 50 55 60 65 70 75 69 .. mt 80 85 90 Abundance #2769:3,4-Dideuterio-1-methylpyrazole 84 14-4 — ■ ( i ■ ■ ' • i • ’ 4.60 4.80 5.00 5.20 m/ z 41.10 32.69% 5000 42 55

0 • ’ I • ‘ 1 » I • » • ’ J ‘ ‘ • l ‘ ‘ ‘ 1 I ‘ ’11’1’1131 ‘ * 1 ‘ “ * I ‘ ‘ “ I ‘ ‘ “ i * “ ’ I ’ 1’44144 ‘ • i‘1 • ‘ । ■ ■ n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 4.60 4.80 5.00 5.20

02719.D HP022102.M Fri Mar 01 10:07:34 2002 Page 8

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