GCMS analysis results for sample AE03075, March 5 2002

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Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02FEB28\02714.D Vial: 4 Acq On : 28 Feb 2002 1:00 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 28, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 3 1-Methyl-l-propynylhydrazine Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 3.99 0.06 ug/L 22990 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1-Methyl-l-propynylhydrazine 84 C4H8N2 000000-00-0 4 2 1-DEUTEROPROPANE 45 C3H7D 020717-73-1 4 3 Hydrazine, 1-methyl-l-(2-propynyl) - 84 C4H8N2 007422-82-4 4 4 2-DEUTEROPROPANE 45 C3H7D 020717-74-2 4 Abundance Scan 55 (3.995 min): 02714.D (-) m/z 45.10 100.00% 45

5000 84 41 55 N 3.60 ‘ 3.80 4.00 4.20 4.40 51 ob 1’117171111119111131310030610131 n i ■ 11 n 11 PTTFI 11111111 u 11111 ■ i |i >tI 1111 ‘144441 m/z 83.95 31.77% miz-> 5

Moow/ 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3163: 1-Methyl-1-propynylhydrazine 45

5000 1 I ' ■ ■ • i ■ • • ■ i ■ ■ ‘ ■ i ■ ■ ■ ■ i ■ ■ 84 3.60 3.80 4.00 4.20 4.40 m/z 55.05 23.70% 2730 38 42 54 66 ob —pm mpptmH A niz-> 5 10 15 20 25 30 35 40 45 50 55 60 a 70 75 80 85 90 Abundance #226: 1-DEUTEROPROPANE 29

3.60 ‘ ■ i 1 ' 3.80 4.00 014.,0...4.20 4.40 45 m/z 43.10 22.68% 5000

42 15 0b ''111'' 11 ■ ■ ■ !■■'' 1 26 m 38 1 ‘ ‘ I “ ‘ ‘ I “ “ I ‘ '1' 1 miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 30 1 * | * * *1 | *1 rfTTri । r i u । _ , A/ . Abundance #3164: Hydrazine, 1-methyl-1-(2-propynyl)- 45 3.60 3.80 4.00 4.20 4.40 m/z 41.10 16.38% 5000 A 84

m/z—> 0- 5 2730 -H 38 42 54 66 mHmpmH 10 15 20 % 30 35 40 45 50 55 60 65 70 75 80 85 90 AM 3.60 3.80 4.00 4.20 4.40

02714.D HP022102.M Fri Mar 01 10:07:00 2002 Page 5

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