GCMS analysis results for sample AE02713, March 5 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\5 9 7 3N\02FEB28\02713.D Vial: 3 Acq On : 28 Feb 2002 12:10 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 2 8, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 3 1-Methyl-l-propynylhydrazine Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 4.01 0.05 ug/L 18448 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1-Methyl-l-propynylhydrazine 84 C4H8N2 000000-00-0 4 2 Hydrazine, 1-methyl-l-(2-propynyl)- 84 C4H8N2 007422-82-4 4 3 Formamide (CAS) $$ Methanamide $... 45 CH3NO 000075-12-7 4 4 Formamide 45 CH3NO 000075-12-7 4 Abundance Scan 56 (4.006 min): 02713.D (-) m/ z 45.10 100.00% 45

5000 84 55 i 1 ■ ■ • i ■ • 3.60 3.80 01 • * t ‘ • i • • ‘ * i * * *' i • ‘1 *! ‘* i • • ■11' * * ■ ir * '"I"1 **1*-**p—***m*d21***12*** p-n-rp-rTT m/z 84.00 42.01% niz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3163:1-Methyl-1-propynylhydrazine 45 mywwneo 5000 11 i 1 ' 84 3.60 3.80 4.00 4.20 4.40 m/z 43.10 29.16% 2730 38 42 54 0+ “ ।1 • ■ ■ । • ■ ■ ■ ।'1 ■ ■ । • •1 ■ । ‘’ I ■ ■11111'111 ‘11 TTHpp ...... Up.. .,■■■■ 66 mfe-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3164: Hydrazine, 1-methyi-1-(2-propynyl)- 45 /A A . 3.60 3.80 4.00 4.20 4.40 5000 m/z 55.00 26.08% 84

2730 38 42 54 66 Of —mmmmp nmmpm niz-> 5 10 15 20253035404550556065 70 75 808590 Abundance #241: Formamide (CAS) $$ Methanamide $$ Carbamaldehyde $$... ... l i.. i... 1 1 ■ ■ i ■ ■ ■ 1 i ' ' ■ • i ' ' ' ■ 1 1 ' 45 3.60 3.80 4.00 4.20 4.40

5000

n/z-> 0 12 , TTH 17

—A HPTTH42 29

5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 A m/ z 44.10

A 21.32%

3.60 3.80 4.00 4.20 4.40

02713.D HP022102.M Fri Mar 01 10:06:53 2002 Page 5

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