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GCMS analysis results for sample AE00465, Jan 18 2002

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Laboratory report documenting gas chromatography-mass spectrometry analysis of environmental sample AE00465 conducted on January 18, 2002.

NYC-WTC_000051222–000051235

Folder label: “GCMS X 1/8/02 A 1/10/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02JAN10\00328.D Vial: 1 Acq On 10 Jan 2002 2:49 pm Operator: Sample : 508 scan ext 1/8 Inst : Instrumen Mise : January 10, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 2 1-methoxy-2-methylidenecycl... Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 4.85 0.17 ug/L 53766 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 1-methoxy-2-methylidenecycloprop... 84 C5H80 019750-15-3 22 2 Formamide, N-(cyanomethyl) - 84 C3H4N20 005018-27-9 9 3 1-Hexene, 6-bromo- 162 C6HllBr 002695-47-8 9 4 2-Pentyn-l-ol 84 C5H8O 006261-22-9 9 Abundance Scan 129 (4.847 min): 00328.D (-) m/z 84.05 100.00% 84 55 41 5000

4.40 4.60 ' 4.80 5.00 5.20

OTP ■ t ■ ■ ■ ■ । ■ i ■ । ■ i ■ ■ - ■ i ■ i ■ ■ ■ ■ i ■ ■ ■ ■ । TT m/z 55.1.0 65.09% m!z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #3302:1-methoxy-2-methylidenecyclopropane$$ Cyclopropane... 83 39 55 -.... .... ......... 5000 69 4.40 4.60 4.80 5.00 5.20 m/z 83.10 60.36%

/z-> 0 20 m LL I......... 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #3103: Formamide, N-(cyanomethyl)- 29

84 4.40 4.60 4.80 5.00 5.20 55 m/z 41.10 51.04% 5000

40 fl 66 0- HHHr 1' ■ i ■ ■ ■ ■ i' । ■ ■ ■11''1111 ■' ■ ।'1 ■111 ■'' । l1' " I ' m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #61498:1-Hexene, 6-bromo- 41 4.40 4.60 4.80 5.00 5.20 m/z 39.10 44.85% 83 5000 67

136 162 O-r 1 • i' •I I " " I 1 " 'T1 1 " I " ' 1 1 4 • 11 । 1 > । ■ >. > । I! । ' [ । mlz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 440 4.60 4.80 5.00 5.20

■0328 .D SCAN508 .M Fri Jan IT 10:08:21 2002 Page 4

NYC-WTC_000051229

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NYC-WTC_000051229Source: NYC Law Department, mirrored locally

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