GCMS DFTPP calibration report, Feb 5 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02FEB05\30648A.D Vial: 5 Acq On 5 Feb 2002 2:03 pm Operator: Sample : 508 scan; re-ext Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\HP020702.M (RTE Integrator) Title : 508 scan method Library- : C:\DATABASE\WILEY7N.L ******************************************************** * ********** * * Peak Number 4 Butane, 2-methoxy-2-methyl-... Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 5.92 0.27 ug/L 204490 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Butane, 2-methoxy-2-methyl- $$ E... 102 C6H140 000994-05-8 36 2 3-(CYCLOHEX-3’ -EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 33 3 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 33 4 N-Ethylformamide $$ N-Formylethy... 73 C3H7NO 000627-45-2 9 Abundance Scan 223 (5.920 min): 30648A.D (-) m/z 73.10 100.00% 73

n/z-> 5000

0- yossposvopa 20 30 43

40 55 1 i 11 ■1 •11 •' ■ ■ i' 50 60 70 87 103 80 90 100 110 120 130 140 150 160 170 180 5.60 m/z 5.80 6.00 43.10 L 1 ' । ■ ■ ■ 1 । 6.20 22.04% Abundance #9702: Butane, 2-methoxy-2-methyl- $$ Ether, methyl tert-p... 73

5000 /Minis 5.60 5.80 6.00 6.20 ' ■ i ■ ■ ■ ' i

55 87 m/z 41.10 10.19% 271 45

nz-> 0 20 -P +—*] 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138:3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1 -p... 73 A —A 5.60 5.80 6.00 6.20 5000 m/z 45.10 8.65% 43 27 55 , 87 113 174 0- ■ i'11 ■ i' TTT ■ r " ■ i1 ■ ■ ‘I’ 1 " 111111 " 111" " i11" i ■' ■11 " ' ■ r ■ " i' " ‘ i'1 ■ ■ 11'111' m/z—> Abundance 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester N A 117’ *I 73 5.60 5.80 6.00 6.20 m/z 71.10 7.61%

5000

43 27 55 87 113 174 0 - 1 r '111 ■' • ‘i' I" I"1'11.. TTT I11111"" I i ■ ■ ■ ■ i ' I " " 11 ' • i ■ ■ ■ ■ i ■ ' ■ ■ i ■ ■ ■ ■ i 1 ' ' 1 i m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5,60 5.80 6.00 6.20

30648A.D SCAN508.M Thu Feb 21 10:19:04 2002 Page 6

NYC-WTC_000004923