GCMS results for sample AE00699, Jan 29 2002

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Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\02JAN16\00699.D Vial: 4 Acq On : 16 Jan 2002 1:20 pm Operator: Sample : 508scan Inst : Instrumen Mise : January 16, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 5 Acetic acid, 3-[1,3]dioxola... Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

5.89 4.22 ug/L 1345940 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H1404 000000-00-0 36 2 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 36 3 Butane, 2-methoxy-2-methyl- $$ E... 102 C6H14O 000994-05-8 33 4 N-Ethylformamide $$ N-Formylethy... 73 C3H7NO 000627-45-2 9 [Abundance Scan 220 (5.886 min): 00699.D (-) m/z 73.10 100.00% 73

5000 43 5.60 5.80 6.00 6.20

n/z-> 0 111 20 30 1' 4 TT Monarphin 40 90 50 60 70 80 87 103 i ■1'11 100 110 120 130 140 150 160 170 180 m/z 43.10 23.53%

Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73

5000: ■ । i rr । r TTr 5.60 5.80 6.00 6.20 43 m/z 41.10 9.01% 27 55 87 113 174 0-TTTTr ' i ■ ■ ■ ■ i ■ ■' ■ i' Mr ■ 1,1 i 1 ■ ■ ■ i 1 1 ■ ' i ■ ■ i 1 ■ ' 1 i i" " p "11 r ITr rn/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138: 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 73 5.60 5.80 6.00 6.20 5000 m/z 45.10 8.92%

43 27 87 174 o1— '111551111''111 113 m/z->20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #9702: Butane, 2-methoxy-2-methyl- $$ Ether, methyl tert-p... 73 5.60 5.80 6.00 6.20 m/ z 71.10 6.31%

5000 55 87

m IT _ I | ( _

27 45 O-T rri l 1" H TTT TT 111'11 m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20

00699.D SCANS08. M Thu Jan 17 08:17:01 2002 Page 7

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