GCMS DFTPP calibration report, Feb 5 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02FEB05\30648A.D Vial: 5 Acq On 5 Feb 2002 2:03 pm Operator: Sample : 508 scan; re-ext Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP020702.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 5 Cyclohexanone Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 7.19 0.25 ug/L 189149 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclohexanone 98 C6H10O 000108-94-1 91 2 Cyclohexanone (CAS) $$ Anon $$ A... 98 C6H10O 000108-94-1 91 3 Cyclohexanone 98 C6H10O 000108-94-1 91 4 Cyclohexanone $$ Anon $$ Anone $... 98 C6H10O 000108-94-1 91 Abundance Scan 334 (7.187 min): 30648A.D (-) m/z 55.10 100.00%

42 5000 98 69 — 83 6.80 7.00 7.20 7.40 7.60

m/z-> 0 1' i " ■' r " ' i" " i —LA1H 1 I " " 11"1111 hosja 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 ‘i’r ‘‘1‘ m/ z 42.10 65.40% Abundance #7094: Cyclohexanone 55 42

5000 ' i ' ' ' ■ i ' ■ 98 6.80 7.00 7.20 7.40 7.60 69 m/z 98.10 43.93% 27 83 Of " I" " i" " 11 -H 1" ■ r ■ " 11111111" I" " 111 m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105

..... R..... Abundance #7092: Cyclohexanone (CAS) $$ Anon $$ Anone $$ Nadone $$ H... 42 55

6.80 7.00 7.20 7.40 7.60 5000 m/z 69.10 30.54% 27 98 69

n/z-> । 01 “ I' ‘ " P ।" 11"1111111 38 mm I ■ j" " ..... IPpu " ■ i' “ ' r ‘ ■ 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 "1 | 83

Abundance #7093: Cyclohexanone ■ i 1 ■ ■ ' i ■ ■

42 55 6.80 7.00 7.20 7.40 7.60 m/ z 41.10 28.28%

5000 27 69 98

/z-> 0 " I " ' ‘ 1 ■ 38 ... ill.. 111 " mmmm 'I ""!■ ■' * 1111111111 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 83 .. 0. M, 6.80 7.00 7.20 7.40 7.60

30648A.D SCAN508.M Thu Feb 21 10:19:04 2002 Page 7

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