GCMS instrument data file SCAN508, Jan 31 2002

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Library Search Compound Report

. Data File : C:\MSDCHEM\1\5973N\02JAN31\00845.D Vial: 6 Acq On : 31 Jan 2002 6:51 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 31, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 6 Cyclohexanone, 2-ethyl- Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T.

13.07 0.32 ug/L 219705 Naphthalene-d8 13.19

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclohexanone, 2-ethyl- 126 C8H14O 004423-94-3 46 2 Cyclohexanone, 2-ethyl- (CAS) $$... 126 C8H140 004423-94-3 43 3 1-Octene, 2-methyl- (CAS) $$ 2-M... 126 C9H18 004588-18-5 42 4 Cyclooctanone 126 C8H140 000502-49-8 38 Abundance Scan 849 (13.067 min): 00845.D (-) m/z 98. 10 100.00% 98 126 84 5000 58 140 42 70 112 155 44 12.80 13.00 13.20 13.40 0 i1'' IIT 1 1 11111। ' 1 ■ i •' !. .। .. I ' ' ' ’ I ' ' * 'Trv 11 1 1 ■ I ■ ’ 1 1 I ‘ 1 m/z 126.10 74.32% m/z-> 60 70 80 90 100 110 120 130 140 150 160 Abundance #22844: Cyclohexanone, 2-ethyl- 98 55

5000 42 83 12.80 13.00 13.20 13.40 126 27 70 m/z 84.05 59 29% 111

m/z-> 01 ■ i ■ '1' i ■' 1 r i 20 30 40 ’ I’’ ' l '1 50 60 70 80 90 100 110 120 130 140 150 ■ ’ i ■ ana/.. .. ■ i'' 11 ‘1111 ■1 160 Abundance #22845: Cyclohexanone, 2-ethyl- (CAS) $$ 2-Ethylcyclohexan... 98 ' 1 i~ l ‘ ■ 1 ■ । V: . . । in । 1 55 12.80 13.00 13.20 13.40 5000 42 83 m/z 83.10 56.49% 126 27 70

. K 111 0 ' 11 11 ' I 1 1 1 1 1 T-p-T ........ I.......... i ’ ■111 ■1111 ■1 ’11 ' ' i ' • ' ' 1 1 1 i '''111''1 1 m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #23113: 1-Octene, 2-methyl- (CAS) $$ 2-Methyl-1 -octene $$ ... 84 98 11 1 126 12.80 13.00 13.20 13.40 53 68 m/z 58.10 44.92%

A. 5000

m/z-> Opm ।, i P 20 30 40 । J.. 11 > 50 60 ‘1′11′11 70 80 TIT 90 1 T I— T-p-rTT-p-T

100 110 120 130 140 150 160 12.80 13.00 13.20 13.40

0845.D SCAN508.M Fri Feb 01 09:19:35 2002 Page 8

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