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GCMS instrument data file SCAN508, Jan 31 2002

Machine-extracted title · confidence 90%

Instrument output file from GCMS analysis using method SCAN508 showing response for deuterated internal standards.

NYC-WTC_000052205–000052221

Folder label: “GCMS X 1/11/02 A 1/31/02

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NYC 9/11 Public Portal Document

Library Search Compound Report . Data File : C:\MSDCHEM\1\5973N\02JAN31\00845.D Vial: 6 Acq On : 31 Jan 2002 6:51 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 31, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 4 Cyclohexanone, 2-(dimethyla... Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

11.26 1.62 ug/L 773757 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclohexanone, 2-(dimethylamino)... 141 C8H15NO 006970-60-1 59 2 Acetonitrile, (dimethylamino)- (... 84 C4H8N2 000926-64-7 43 3 N-Methyl-L-prolinol $$ (S)-(-)-l... 115 C6H13NO 034381-71-0 37 4 Piperidine, 2-methyl- (CAS) $$ 2... 99 C6H13N 000109-05-7 32 Abundance Scan 691 (11.263 min): 00845.D (-) m/z 84.05 100.00% 8|4

42 126 5000

98 141 56 70 11.00 1120 11.40 11.60 m/z-> 20 Oh 1 ' i 1 30 1 ill 40 50 60 ....I'... 70 80 90 ''I''1'11111 r1'''I' ■ 100 110 120 130 ' I ' 1 ' 1 1' 140 50.53% Abundance #37080: Cyclohexanone, 2-(dimethylamino)- $$ 2-(Dimethylam... 84

5000 T 11.00 11.20 11.40 11.60 42 70 m/z 126.10 45.61% 58 113 141 77 98 Oh ■ ■ i ■ ——I , 1 „ I l r r -+ ............ I l . . . ■ I m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #3160: Acetonitrile, (dimethylamino)- (CAS) $$ N.N-DIMETHY... 84 1 1 , 1 1 ' 1 1 '1 , 1 1 .... । । ।

11.00 11.20 11.40 11.60 5000 m/z 41.05 20.80% 43

n/z-> Abundance Oh 20 ■ ■ i ■ 30 -l..52.777. 67..... I 40 50 60 70 80

84 90 100 110 #15955: N-Methyl-L-prolinol $$ (S)-(-)-1-Methyl-2-pyrrolid... 120 130 140 W/U P—

m/z 11.00 11.20 11.40 11.60 44.10 19.14% 5000 42 30 57 70 | !............................ 115.......................... OhITTTTT ----- /z-> 20» 30 40 50 60 70 80 90 100 110 120 130 140 11.00 11.20 11.40 11.60

30845.D SCAN508.M Fri Feb 01 09:19:35 2002 Page 6

NYC-WTC_000052212

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NYC-WTC_000052212Source: NYC Law Department, mirrored locally

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