GCMS surrogate recovery results for sample AE00282, Jan 2002

NYC 9/11 Public Portal Document Data File : C:\MSDCHEM\1\5973N\02JAN09\282.D Vial: 7 Acq On : 9 Jan 2002 11:12 pm Operator: Sample : 508 scan ext 1/7 Inst : Instrumen Mise : January 9, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 1 2-Buten-l-ol, 3-methyl- Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T. 4.63 0.14 ug/L 54547 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Buten-1-ol, 3-methyl- 86 C5H10O 000556-82-1 53 2 2-Buten-l-ol, 3-methyl- (CAS) $$... 86 C5H10O 000556-82-1 53 3 2-Buten-l-ol, 3-methyl- (CAS) $$... 86 C5H10O 000556-82-1 38 4 2-Buten-l-ol, 3-methyl- 86 C5H10O 000556-82-1 38 Abundance Scan 110 (4.629 min): 282. D (-) m/z 71.10 100.00% 41 71 57 88

5000 53 85 TTIIr N MA..... 49 4.20 4.40 4.60 4.80 5.00

n/z-> Ol 110911000911 20 25 30 35 40 45 ‘Is ‘It 50 i ■ ■ ■ ■ i ■ ■ ■ ■ i 55 60 65 70 .......HiI..... 75 80 85 90 95 m/z 41.101 93.13%

Abundance #4069: 2-Buten-1-ol, 3-methyl- 7h

5000 27 39 53 4.20 4.40 4.60 4.80 5.00 68 m/z 57.10 72.48% 31 86

T)/Z-> Ol ‘Ir 20 25 L 30 35 40 45 50 55 60 65 49 1 1 1 " ' 11 59 11'1111' A 1 " I " " I " '111 " rp TTTr 70 75 80 85 90 95 Abundance #4072: 2-Buten-1-ol, 3-methyl- (CAS) $$ Prenol $$ 2-METHYL... 7|1 H 4.20 4.40 4.60 4.80 5.00 5000 27 39 m/z 88.00 67.51% 53

68

m/z-> 0 20 25 „L. 31 49 TVUTPTTT 30 35 40 45 50 55 60 65 70 75 80 85 90 ,1,59... Uh . ........ l.... 95 86 1111'

Abundance #4073:2-Buten-1-ol, 3-methyl- (CAS) $$ Prenol $$ 2-METHYL... 67 71 4.20 4.40 4.60 4.80 5.00 53 39 m/z 53.00 43.17% 27 5000

42 86 491 0 ■ i• • • ■ i• । I'I "I""!1' IPPTT TTT —TPTPTHT 111 1' 1 i ■ ' ---- l-r-r-r-r-p-r TTu‘T‘‘r‘0— n/z—> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 4.20 4.40 4.60 4.80 5.00

282.D SCAN508.M Thu Jan 10 11:52:04 2002 Page 3

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