GCMS surrogate recovery results for sample AE00316, Jan 2002

NYC 9/11 Public Portal Document Data File : C:\MSDCHEM\1\5973N\02JAN10\00316.D Vial: 3 Acq On : 10 Jan 2002 10:07 am Operator: Sample : 508 scan ext 1/7 Inst : Instrumen' Mise : January 10, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 2 3-Buten-2-ol, 2-methyl- Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 5.01 0.19 ug/L 57471 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

l 3-Buten-2-ol, 2-methyl- 86 C5H10O 000115-18-4 59 2 Butenol, methyl- 86 C5H10O 060766-00-9 59 3 3-Buten-2-ol, 2-methyl- $$ .alph... 86 C5H10O 000115-18-4 45 4 Methyl 1-Methyl-2-propenyl Ether 86 C5H10O 000000-00-0 38 Abundance Scan 143 (5.006 min): 00316.0 (-) m/z 43.10 100.00% 43 71

5000 55 59

39 AAAAAAALAAA n/z-> - 01 ■' r r " i' " ' i' " ■ r " ' i " 5 la— 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 84 mmmPPWTP 4 60 m/z 4.80 71.10 5.00 5.20 5.40 94.85% Abundance #4083: 3-Buten-2-ol, 2-methyl- 71 43

5000 . / A...... ... 59 4 60 4.80 5.00 5.20 5.40 27 31 m/z 41.10 88.30% 53 0 r"'i 37.— । ‘ 1111 ■ ■ 1111 • —P 1........ 86..... m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #4093: Butenol, methyl- 43 7h AAWLLA4 4.60 4.80 5.00 5.20 5.40 5000 59 m/ z 69.10 64.49% 27 15 31 53 67 m/z-> 01 ' "TV'' "I'"'I' TIT ■ > i ■ ■ ■ • i ■ ■ HHHH ...... . 1-11 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 1........ 86..... Abundance #4082: 3-Buten-2-ol, 2-methyl-$$ .alpha ,.alpha.-Dimethyl... 7h 4.60 4.80 5.00 5.20 5.40 m/z 55.00 40.91% 43 5000 59 27 31

/z—> 01 ‘ I’ 15 - TTHTTT ‘T‘ 53 i ......... 86..... 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 . 67 4.N.. 4.60 4 80 5.00 5.20 5.40

00316.D SCAN508.M Thu Jan 10 11:52:12 2002 Page 4

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