GCMS analysis results for sample AE00470, Jan 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\1\5973N\02JAN15\00470.D Vial: 4 Acq On : 15 Jan 2002 12:42 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 15, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 3 3-Buten-2-ol, 2-methyl- Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 5.01 0.24 ug/L 77600 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Buten-2-ol, 2-methyl- 86 C5H10O 000115-18-4 86 2 Butenol, methyl- 86 C5H10O 060766-00-9 86 3 3-Buten-2-ol, 2-methyl- (CAS) $$... 86 C5H10O 000115-18-4 72 4 3-Buten-2-ol, 2-methyl- $$ .alph... 86 CSH100 000115-18-4 72 Abundance Scan 143 (5.006 min): 00470. D (-) m/z 71.10 100.00% 43 71

5000 — 59 39 51 55 -A 4.60 4.80 5.00 5.20 5.40 - TImu—tt—n , 86 Or 11010 — - m/z 43.10 83.98% n/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #4083:3-Buten-2-ol, 2-methyl- 71 43

5000 59 4.60 4.80 5.00 5.20 5.40 27 31 m/ z 41.10 61.48% 53

n/z-> 0 —37 -- H " i " " i"' ■ i" " i ■ ‘ I 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #4093: Butenol, methyl- 43 71 - , Ah,, A|^,... 4.60 4.80 5.00 5.20 5.40 5000 59 m/ z 59.10 39.49% 27 15 31 53

m/z-> 01 " i" ‘TT '' i " " i " . ..... 1. 1.1.. I + 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 —7 17........ .,0111 Abundance #4081: 3-Buten-2-ol, 2-methyl- (CAS) $$ 2-Methyl-3-buten-2... A-pp -4.60 A / 7h 4.80 5.00 5.20 5.40 m/z 69.10 33.43% 5000 43 A 59 27 31 53 67 n/z-> 0 5 p-i ‘II’’’ . ITTT’I + TmTTTT — — 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 4.60 4.80 5.00 5.20 5.40

>0470.D SCAN508.M Wed Jan 16 08:13:51 2002 Page 5

NYC-WTC_000051705