GCMS analysis results for sample AE00470, Jan 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\1\5973N\02JAN15\00470.D Vial: 4 Acq On : 15 Jan 2002 12:42 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 15, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1... \SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 2 1-methoxy-2-methylidenecycl... Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T. 4.85 0.15 ug/L 48009 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1-methoxy-2-methylidenecycloprop... 84 C5H80 019750-15-3 17 2 1-PROPENYL-AZIRIDINE 83 C5H9N 000000-00-0 16 3 2-Pentyn-l-ol 84 C5H80 006261-22-9 10 4 (Z)-1-Propenylaziridine $$ Aziri... 83 C5H9N 024461-38-9 7 Abundance Scan 129 (4.846 min): 00470.D (-) m/z 83.95 100.00% 84

41 55 59 5000

44 . 4.40 4.60 4.80 5.00 5.20 1 49 0 ' ' I' ' ' ' I '' 1 ' I ' ' '' I' ' TT - I 11 1 ‘ I ' ' '' I ' ' 1 ' I '' ' ' 1 1 ' I 1 1 1 ' I ' ' m/z 41.10 59.01% n/z—> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3302:1 -methoxy-2-methylidenecyclopropane $$ Cyclopropane... 83 39 55

5000 69 AN, N . No, A 4.40 4.60 4.80 5.00 5.20 ' 45 m/ Z 83.00 54.76% 51 0 ----- TT - ■ ■ i ■1 I ' ■ 1 ' i '1 ' 1 1 1' -P m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3059:1-PROPENYL-A2IRIDINE 41 55 83 i ' ’ ' ' i ' ' 4.40 4.60 4.80 5.00 5.20 5000 m/ z 55.10 54.07% 27 68

m/z-> 0 ' ’ i1 ' ' ' i 20 25 '' i'' " I'' 30 35 40 mm He.... Ji.... .. 1 1' 45 50 55 60 65 70 75 80 80 111' 1' i ■ ■ 85 90 Abundance #3291: 2-Pentyn-1-ol 39 4.40 4.60 4.80 5.00 5.20 m/z 59.10 51.68% 83 5000 27

44 51 66 -

m/z-> 0 ■ 111'1 ■ i 1 20 25 m —130 35 40 45 50 55 --

60 65 70 75 80 85 111'1 90 -A 4.40 4.60 4.80 5.00 5.20

00470.D SCAN508.M Wed Jan 16 08:13:50 2002 Page 4

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