GCMS surrogate recovery results for sample AE00280, Jan 2002

NYC 9/11 Public Portal Document Data File : C:\MSDCHEM\l\5973N\02JAN09\280.D Vial: 5 Acq On 9 Jan 2002 9:31 pm Operator: . Sample : 508 scan ext 1/7 Inst : Instrumen Mise : January 9, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 3 2-Buten-l-ol, 3-methyl- (CA... Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. 4.63 0.16 ug/L 80903 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Buten-l-ol, 3-methyl- (CAS) $$... 86 C5H10O 000556-82-1 49 2 2-Buten-l-ol, 3-methyl- (CAS) $$... 86 C5H10O 000556-82-1 47 3 2-Buten-l-ol, 3-methyl- 86 C5H10O 000556-82-1 47 4 2-Buten-l-ol, 3-methyl- $$ .gamm... 86 C5H10O 000556-82-1 47 Abundance Scan 110 (4.630 min): 280. D (-) m/z 41.10 100.00% 4 71 88 57

5000

51 101 AM . ... A 4.60 n/z-> Ol l1 ■b ■ i ■ ■ ■'i■ ■■' i 4 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 ' r " ' i'' " i 1111 ■ " r 4.20 m/z 4.40 71.00 4.80 5.00 92.85% Abundance #4075:2-Buten-1-ol, 3-methyl- (CAS) $$ Prenol $$ 2-METHYL... 7h 41

5000 53 4.20 4.40 4.60 480 5.00 86 m/z 88.00 86.02% .............. ... ........... n/z-> 0 TT‘ I ■ ■1 -I l1 ■■ I 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 p + Abundance #4072:2-Buten-1-ol, 3-methy)- (CAS) $$ Prenol $$ 2-METHYL... 71 A . 4.20 4.40 4.60 4 80 5.00 5000 27 39 53 m/z 57.00 70.62%

86 0 ll TTTTTT I' 5.sl + 11111.।।।।। . m/z-> Abundance 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 #4069: 2-Buten-1-ol, 3-methyl- 71 1 0___ .....A.!, 4.20 4.40 4.60 4.80 5.00 m/z 43.10 46.44%

5000 27 39 53

n/z-> 0 ।" " । L p-rrty 5.l *H 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 86 ।■■•■। । p om, 4.20 4.40 4.60 4 80 5.00

280.D SCAN508.M Thu Jan 10 11:51:54 2002 Page 5

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