GCMS analysis results for sample AD31647, Jan 25 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02JAN22\31647.D Vial: 3 Acq On : 22 Jan 2002 1:51 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 22, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1... \SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 8 4-METHOXY-.BETA.-METHYLCINN... Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T.

22.28 0.13 ug/L 72433 Phenanthrene-dl0 22.63 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 72 2 Thiocyanic acid, 2-benzothiazoly. .. 192 C8H4N2S2 006011-99-0 59 3 Phenanthrene, 9-methyl- $$ 9-Met... 192 C15H12 000883-20-5 59 4 l-amino-2-methyl-4-isopropyl-thi... 192 C5H13N4PS 107264-54-0 50 Abundance Scan 1656 (22.280 min): 31647.D (-) m/z 192.10 100.00% 192

5000 . .................................. . 96 146 160 22.00 2220 22.40 22.60 mz—> 60 —aosgenosilia 82 4 122 | • i ■ ■ ■ • i • ■ ■ ■ i ■ ■ ■ ■ i ■ • ‘ ■ i ■ 70 80 90 100 110 120 130 140 150 160 170 180 190 200 ■■i ■ ‘' ■ i ■ ■ ■' I m/z 191.10 17.21% Abundance #102588: 4-METHOXY-.BETA-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

108 1 ■ ' i ■ ■ ■ ■ i ■ ■ ‘ ■ i ■ ■ ■ ■ i ■ ' ■ ■ 5000 22.00 22.20 22.40 22.60 146 175 m/z 96.10 16.22%

' ■ i' ■ ■ ■ i' ■' ■ i ■ ■ ■ ■ i11 ■ ■ i ■' i ■ ■ ■ ■ i ■ ■ ■ ■ i ■1 ■' i ■ ■ ’ i ■ ‘■ i ■' ■' i ■ 1 ■ । ‘ । Tptt niz-> 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102098: Thiocyanic acid, 2-benzothiazolyl ester (CAS) $$ ... 1:2

22.00 22.20 2240 22.60 5000 m/z 146.10 14.07%

134 “376 90 108 niz-> mH 148 160 mIWmmmmm 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 122 ■ i11'111

Abundance #103936: Phenanthrene, 9-methyl- $$ 9-Methylphenanthrene ..S..... ... 192 22.00 22.20 22.40 22.60 m/z 193.10 13.89%

5000

96 _ _ 165 176 mk-> irpr .. 88.1 139 152 .| ‘ i ■ “ ■ i ■ ■ ■ ‘ i ■ ■ ■ ■ i ■ • ■ ■ i' • • • i ■1 ■ • i * • * ■ i • 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 ■1 i ■1 22.00 22.20 22.40 22.60

31647.D SCAN508.M Thu Jan 24 13:55:41 2002 Page 10

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