GCMS sample analysis report AE05844, Apr 18 2002

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Library Search Compound Report

Data File : C:\HPCHEM\l\DATA\APR1202\5844.D Vial: 20 Acq On : 16 Apr 2002 2:42 am Operator: Sample : re-extract Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C : \DATABASE\NBS7 5K. L Peak Number 2 Cyclopentasiloxane, decamethyl Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 14.83 0.34 ug/1 57885 Naphthalene-d8 15.87 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclopentasiloxane, decamethyl- 370 C10H3005Si5 000541-02-6 2 N-(Trifluoroacetyl)-N,0,01,01'-tetr 553 C22H42F3NO4Si4 000000-00-0 43 3 Benzoic acid/ 2,4-bis[(trimethylsil 370 C16H30O4Si3 010586-16-0 37 4 Phenethylamine, N-methyl-.beta.,3,4 399 C18H37NO3Si3 010538-85-9 37 Abundance Scan 1066 (14.829 min): 5844. D (-) m/ z 72.95 100.00% 73

5000 267 355

J 1B33 45 14.40 14.60 14.80 15.00 15.20 ■ ’50 ' 1 ... 1 1 ' ' i 154 1 193 1 1 237.i 1 ' ' 1 i ■ i ' ■ 1 ■ ' 323 | ' i ' ■ 1 ■ i 1 ‘ 1 1 i ' r ' 1 i 1 1 ■ ' i 1 1 1 1 i ' 1 m/z 355.05 45.83% m/z-> 100 150 200 250 300 350 400 450 500 550 Abundance #51266: Cyclopentasiloxane, decamethyl- 73

355 267 ,..... 5000 14.40 14.60 14.80 15.00 15.20 m/z 2 67.00 41.09% 207 323 •I** m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #60162: N-(Trifluoroacetyl)-N,O,O',O"-tetrakis(trimethylsi 73 - 355 14.40 14.60 14.80 15.00 15.20 5000 m/z 356.05 16.13%

45 | „ —————— 147 193 267 ———————————————— III*’I’I’’II’ III 538 1 1 i ' ’— I I II ’ . m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #73975: Benzoic acid, 2,4-bis[(trimethylsilyl)oxyJ-, trimet 73 14.40 14.60 14.80 15.00 15.20 m/ z 2 68.00 11.77% 5000 355 45 133 193 223 281 ------- i ■ 1 ' ‘ i 1 ■ 1 i ' > 1 > । । > m/z—> 50 100 150 200 250 300 350 400 450 500 550 14.40 14.60 14.80 15.00 15.20

5844.D GCMS0412.M Wed Apr 17 09:47:15 2002 Page 2

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