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GCMS analysis results, Sample AE05750, April 18, 2002

Machine-extracted title · confidence 100%

Reference standard analysis results for volatile organic compounds used to verify GCMS instrument performance.

NYC-WTC_000048500–000048511

Folder label: “GCMS X 4/10/02 A 4/15/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\APR12O2\575O.D Vial: 19 Acq On : 16 Apr 2002 1:43 am Operator: Sample : re-extract Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 4 Anthracene-dlO- Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

25.75 0.27 ug/1 49939 Phenanthrene-dl0 25.61

Hit# Of 5 Fentative ID MW MolForm CAS# Qual

1 Anthracene/d10- X / 188 C14D10 001719-06-8 /90 ) 2 Phenanthrene-diO 188 C14D10 001517-22-2(90/ 3 Cyclohexanone, phenylhydrazone 188 C12H16N2 000946-82-7 59 4 Naphthalene, 1,7-dimethoxy- 188 C12H1202 005309-18-2 47 Abundance Scan 2255 (25.750 min): 5750.D (-) m/z 188.10 100.00% 188

5000 ...... ............................... 1 1 I’ ' r | ' T 1 ^ | । ' ' । | I ' । । | । 42 52 66 I ■11' 11" ' 111'' ir' ■' r T T —hTpmmmmmm 158 .4... 25.40 25.60 25.80 26.00 m/z 187.10 25.12% m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #19957: Anthracene-d10- 188

5000 .............. ■■1 1 1 r ■ 1 1 _1 । ■ 1■ 1 1 ■ 1 '■1 ■ 25.40 25.60 25.80 26.00 m/z 189.10 14.47% 80 94 160 66 I । ! I I I | I 1 I I | I ! ! ! | ! ! I I | I I TT | I I I r I 11’1 m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #19958: Phenanthrene-d10 188 . - I ■! | I

25.40 25.60 25.80 26.00 5000 rn/z 184.10 12.73%

80 94 160 66 m/z—> 30 40 50 P 60 70 80 A - 90 100 110 120 130 140 150 160 170 180 190 .. Ii,. Abundance #19927: Cyclohexanone, phenylhydrazone T-i-j-rT-TT-pr-l-T-'-prn-T-r-f-rT-'-rj^ 188 25.40 25.60 25.80 26.00 93 m/z 80.05 12.46%

5000 65 77 106 145 120 132 | 159 170 I ' ' ' ' I ' ' ' ' I ‘i’’ IP 1'1 ■' 1 1 ■ । । 1 ■ 1 ■ 1 1 i 1 1 1 ' i ■ miz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 25.40 25.60 25.80 26.00

5750.D GCMS0412.M Wed Apr 17 09:46:59 2002 Page 4

NYC-WTC_000048510

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NYC-WTC_000048510Source: NYC Law Department, mirrored locally

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