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GCMS analysis results, Sample AE08262, April 22, 2002

Machine-extracted title · confidence 100%

GCMS analysis report for sample AE08262 showing surrogate recovery and unknown compound screening on April 22, 2002.

NYC-WTC_000048309–000048332

Folder label: “GCMS X 4/9/02 A 4/17/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\l\DATA\020417\08262.D Vial: 19 Acq On : 18 Apr 2002 12 :18 am Operator: Nefliu Sample : sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98. L ********************************************************************* Peak Number 10 3-(2-Methoxy-5-methylphenyl. ... Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

22.64 0.32 ug/L 473874 Phenanthranene-dl0 23.02

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3 -(2-Methoxy-5-methylphenyl)acry.. . 192 C11H1203 103986-76-1 50 2 Bitoscanate 192 C8H4N2S2 004044-65-9 47 3 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 40 4 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 40 Abundance Scan 3330 (22 645 min) 08262.D (-3322) (-) m/z 192.10 100.00% 1.2

5000-

96 146 160 4 0+ TII 40 Ttt 54 62 70 82 118 -Hm L n".. . u""!1 —p 22.40 22.60 22 80 23.00 m/z 191.10 19.56% n/z- > 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80954: 3-(2-Methoxy-5-methylphenyl)acrylic acid 161 192

5000 105 II 1 ' 1 1 22.40 22.60 22.80 23.00 77 132 91 m/z 146.10 16.23% 39 51 65 115 145 ,

Tl/Z-> 01 ............. . , - . 175 33. • "11111 " I' 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 l Abundance #80930 Bitoscanate 19 2 ----- 22.40 22.60 22.80 23.00 5000 m/z 193.00 14.38% 134 90 160 50 63 75 148 n/z--> 0 26 39 HIr +4+ 99,107 116 —Htp pirputo ' i' ■ ■ ■ ir 1 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033: Phenanthrene, 9-methyl- 192 22.40 22.60 22 80 23.00 m/z160.00 11.77%

5000

96 165 i i 29 39 51 63 75 83 I 115 126 139 152 1 176 0 TRWWIUTTTTTTTTPTTTTTTTTTTTTLTTITTTTTTTTTHTT " 111 I T ■ ’ ' I ■ 1 ' ■ I n/z--> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22 40 22.60 22.80 23 00

08262.D 041702SCAN.M Thu Apr 18 09:49:33 2002 Page 15

NYC-WTC_000048326

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NYC-WTC_000048326Source: NYC Law Department, mirrored locally

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