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GCMS surrogate recovery results, April 22 2002

Machine-extracted title · confidence 100%

Laboratory report detailing surrogate recovery results for sample AE08260 analyzed on April 22, 2002.

NYC-WTC_000048268–000048286

Folder label: “GCMS X 4/9/02 A 4/17/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\l\DATA\020417\08260.D Vial : 17 Acq On : 17 Apr 2002 10:40 pm Operator: Nefliu Sample : sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98.L ********************************************************************* Peak Number 8 Thiocyanic acid, 2-benzothi... Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

22.64 0.33 ug/L 523855 Phenanthranene-dl0 23.02

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 50 2 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 42 3 Phenanthrene, 1-methyl- 192 C15H12 000832-69-9 42 4 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 40 Abundance Scan 3330 (22 645 min): 08260.D (-3320) (-) m/z 192.10 100.00% 192

5000

70 82 96 118 146 160 .. A. A. 22 40 22 60 22 80 23.00 42 52 0- r ■ " i" 1' T11" i11 ■ pthit.. | H....... nnTmti......... . I— m/z 191.00 19.95% n/z- > 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 192

5000 22.40 22 60 22.80 23 00 69 m/z 146.10 13.83%

m H 45 82 98 108 122 134 148 160 oV ------- TIITU l...... ’ n/z- > 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033 Phenanthrene, 9-methyl- 192

22.40 22.60 22.80 23.00 5000 m/z 193.00 11.59%

98 165 i । 29 39 51 63 75 83 1 115 126 139 152 । 176 0-19099** —PmmmmmHpmt 11111 Tl/Z--> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125856: Phenanthrene, 1-methyl- ..... , . 192 22.40 22 60 22 80 23.00 m/z 96.10 11.00%

5000

96 AE

n/Z- > 27 39 51 63 74 82 . 1 0 IUUUTIVOUTITNTTTTTTTT 115 126 139 152 105 178 I +mPmemTTTHmt 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 k 2240 22.60 22.80 23.00

08260.D 041702SCAN.M Thu Apr 18 09:45:55 2002 Page 13

NYC-WTC_000048284

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NYC-WTC_000048284Source: NYC Law Department, mirrored locally

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