GCMS analysis results for unknown compounds, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\060702\12737.D Vial: 13 Acq On 7 Jun 2002 6:21 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 18 Thiocyanic acid, 2-benzothi... Concentration Rank 20 R.T. EstConc Area Relative to ISTD R.T. 22.53 0.24 ug/L 202136 Phenanthranene-dl0 22.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 3 2 1,2-Phenylene diisothiocyanate 192 C8H4N2S2 071105-17-4/53 3 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 45 4 Bitoscanate 192 C8H4N2S2 004044-65-9 42 Abundance Scan 3311 (22.533 min): 12737.D (-3303) (-) m/z 192.10 0.00% 192

5000 ............................ .........................

44 70 82 96 146 160 22.20 22.40 22.60 22.80 0 U 1. 1 . 1 | U . 1 | . 1 . 1 | . 1 ■ 1 [ . 1 1 1 | > > U | 1 1 11 | I > ! 1 | I I 1 1 | I I4t| I I . I | ! > ! I | UTI | I I I 1 | 1 . I > | I rm > | I I I 111 n ■ -rrp-r m/ z 191.00 18.11% m/z-> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 192

.................... 5000 ‘ ’ I ' ' ' ‘ I ’ ' i 1 1 • ' i 1 "II 22.20 22,40 22.60 22.80 m/z 193.00 11.05% 45 । | 90 108 122 134 148 160 0 ■ •। ।। ।‘11 ■ i'“ ।• i ---------++AAHTHHHTTT miz-> 0 1020304050607080 90100110120130140150160170180190200 Abundance #80862:1,2-Phenylene diisothiocyanate 192 1T 22.20 22.40 22.60 22.80 64 5000 m/z 146.10 10.73%

39 50 75 90 134 0 +4.18.2++++ J 107 122 148 160 'I (Il rl’M+rth ''ll ■. l' l'l.' 11 ■'l,l TTTgm M. mtz-> Abundance 0 10 2030405060 70 80 90 100110120130140150160170180190200 #81033: Phenanthrene, 9-methyl- 1912 0 22.20 22.40 22.60 22.80 m/z 96.00 7.78%

5000

29 39 51 63 73 83 %6 115 126 139 152 165 176 I 0 .. ।... > ।. i.. ।... > ।, i. 11... ।..., ।।. n. । J’i rl| ।! 11111 ■ 111 ri 111 < 1111111'| 1111 |'i 11111’1*11 | 1 rh 111 i‛r‛1 Trp-r TI n/z—> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 22.20 22.40 22.60 22.80

12737.D 060302.M Mon Jun 10 11:24:27 2002 Page 21

NYC-WTC_000015249