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GCMS analysis results for sample AE10305, May 2002

Machine-extracted title · confidence 95%

Laboratory report documenting gas chromatography-mass spectrometry analysis of environmental sample AE10305 conducted on May 17, 2002.

NYC-WTC_000045113–000045136

Folder label: “GCMS X 5/1/02 A 5/8/02

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Scanned page image, NYC-WTC_000045127
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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050802\10305R.D Vial: 26 Acq On 9 May 2002 12:56 pm Operator: Mclean Sample re-inj Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 7 Thiocyanic acid, 2-benzothi... Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T.

22.58 0.31 ug/L 357652 Phenanthranene-dl0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 53/ 2 4-Hydroxy-3,5-dimethylcinnamic acid 192 C11H1203 1000132-15-8/42 3 Bitoscanate 192 C8H4N2S2 004044-65-938 4 2-Imidazolidinone, 1-methoxy-3-p... 192 C10H12N2O2 052420-43-6 37 Abundance Scan 3319 (22.580 min): 10305R.D (-3311) (-) m/z 192.10 100.00% 192

5000

_ 82 96 146 160 m 22.20 22.40 22.60 22.80 23.00 42 52 ,70 . ,| 118 0 aT TTITTT 1 ''I'1 mng 111 n m/z 191.10 22.03% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 192

5000 22.20 22.40 22.60 22.80 23.00 m/z 146.10 15.68% 45 68 - 90 108 122 134 I 148 160 A

/z—> 0 H TT TTTTTTTHT 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81030:4-Hydroxy-3,5-dimethylcinnamic acid 192 ,...... ,.4....... . 22.20 22.40 22.60 22.80 23.00 5000 m/z 193.00 12.91% 89 175 L 63 117 145

0 ---H44+4l 45 J 77 105 |7 135 | 163 I r’l'ri | Ittrrt i i i । t‘r i ""rl" 1 । । p'l i i | rrl 11IIII I— mlz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80930: Bitoscanate 192 22.20 22.40 22.60 22.80 23.00 m/z 96.00 11.00% 5000 134 90 160 50 63 75

m/z-> 0 +A-HH+ rrl i | l'i । i 11 । I । |'l । । i । , 107116 20 30 40 50 60 70 80 90 100 110 120 130 140 1 50 160 170 180 190 200 148 i1 "■| i"11 "It ' I " 111 " " I L 22.20 22.40 22.60 22.80 23.00

10305R.D 050102.M Thu May 09 13:51:05 2002 Page 10

NYC-WTC_000045127

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NYC-WTC_000045127Source: NYC Law Department, mirrored locally

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