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GCMS sample analysis results, AE11902, June 3, 2002

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Laboratory report presenting analytical results for target compounds and surrogate recovery data for water sample AE11902.

NYC-WTC_000012881–000012907

Folder label: “GCMS X 5-21-02 A 5-22-02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052202\11902.D Vial: 9 Acq On : 22 May 2002 8:20 pm Operator: Mclean Sample : 5/21 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 17 Thiocyanic acid, 2-benzothi... Concentration Rank 16 R.T. EstConc Area Relative to ISTD R.T. 22.54 0.25 ug/L 244671 Phenant hranene-d10 22.91 Hit# of . 5 Tentative ID MW MolForm CAS# Qual 1 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 53 2 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9/45 3. Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 45 4 5H-Tetrazole-5-thione, 1,4-dihyd... 192 C8H8N4S 1000142-22-5 42 Abundance Scan 3312 (22.539 min): 11902.D (-3305) (-) m/z 192.10 0.00% 192

5000-

146 160 22.20 22.40 22.60 22.80 A 40 49 70 82 96 118 0 —mmmmp Hp m/z 191.10 16.95% miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 192

5000i 22.20 22.40 22.60 22.80 m/z 146.10 14.69% 45 82 90 108 122 134 148 160 O-Ip pMG 4 na It 111 r e 1111111111 !*> ■ j > 111 ] 11 > r | > ?! 11 > । > i| । > 111 I....... “ ■ i “ miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80953: 2-Propenal, 3-(3,4-dimethoxypheny!)- 152 161 A 22.20 22.40 22.60 22.80 5000 m/z 193.10 12.27% 77 121 149 177 91 103

niz-> 01 mHrH 52 64 HHlH 138 gm m ■ , । ,I 1 , । . ,'I j , , , . a r , . । l‘l 1 I | 1 i ( pi l m 1 1 | nr | I ■ I l —7 I 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 A

Abundance #81033: Phenanthrene, 9-methyl- T ‘ 1****1"*I 4 1****1**I 192 22.20 22.40 22.60 22.80 m/z 96.00 8.91% 5000

29 39 51 63 74 83 A 115 126 139 152 165 176 0-TOUTTTgmTTgr fri l i 1 TII /z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80

11902.D 052202.M Tue May 28 12:06:51 2002 Page 20

NYC-WTC_000012905

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