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GCMS analysis results for sample AE11422, May 2002

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Laboratory report documenting GCMS analysis of sample AE11422 conducted on May 30, 2002.

NYC-WTC_000025464–000025478

Folder label: “GCMS X 5/16/02 A 5/20/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052002\11422.D Vial: 12 Acq On : 20 May 2002 10:14 pm Operator: Mclean Sample : 5/16 eh Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C : \DATABASE\NIST98 . L

Peak Number 6 Thiocyanic acid, 2-benzothi... Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 22.58 0.23 ug/L 180103 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 59 2 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 45 3 Phenanthrene, 1-methyl- 192 C15H12 000832-69-9 45 4 2,4-Diamino-6-(hydroxymethyl)pte ... 192 C7H8N60 000945-24-4 45 Abundance Scan 3318 (22.574 min): 11422.D (-3311) (-) m/z 192.10 100.00% 192

5000 - _ 82 96 146 160 22.20 22.40 22.60 22.80 23.00 40 49 | - 0 1111310—0100-—1-—m—p100130r ' I' ‘" I''' ‘ I " " I' WP m/z 191.10 17.17% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 192

5000 22.20 22.40 22.60 22.80 23.00 m/z 146.10 13.01%| 45 69 90 108 122 134 I 148 160 miz-> 0 1).......... I1"!' .1,7m].. 4 TT 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 ■ I ■ 1" 11 111' ’ < |' ''f 11 > । >1' 11 1 1111

Abundance #125842: Phenanthrene, 2-methyl- 192 0 22.20 22.40 22.60 22.80 23.00 5000 m/z 193.10 12.29%

96 27 39 51 82 63 ,|| 115 126 139 152 165 176 0 ■ i ■ " ' r ' " i " " i " ' ‘ i" i - 11'11 ■ r ' " 111'1 r 111 r 11 rl1" 11'1" 111 l i rI i' ’I T-p-r m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125856: Phenanthrene, 1-methyl- - ‘ I > < । ' । 1 1 1 1 1 1 1 1 1 1 192 22.20 22.40 22.60 22.80 23.00 m/z 160.10 10.99% A 5000

96 4EE 178 n/z-> 27 39 51 63 82 1 0 । । । । । । > > > > । > 1 । । । > । । IT‘‘i 11′111 |'l'i "li 1 1 115 126 139 152 190 1 <1 1 p-ri 1 । 1 1 1 1 । 1 1 rr, 1 1 1 1 |'I i i 1 । I'l'l 1 rirl) 1 it 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 1 - 22.20 22.40 22.60 22.80 23.00

11422.D 050102 ,M Thu May 23 10:49:12 2002 Page 8

NYC-WTC_000025476

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