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GCMS sample analysis results, AE11904, June 3, 2002

Machine-extracted title · confidence 100%

Laboratory report presenting analytical results for target compounds and surrogate recovery data for water sample AE11904.

NYC-WTC_000012937–000012965

Folder label: “GCMS X 5-21-02 A 5-22-02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052202\11904.D Vial: 11 Acq On : 22 May 2002 9:58 pm Operator: Mclean Sample : 5/21 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan T Library- : C:\DATABASE\NIST98.L

Peak Number 14 Thiocyanic acid, 2-benzothi... Concentration Rank 20 R.T. EstConc Area Relative to ISTD R.T. 22.54 0.28 ug/L 301756 Phenanthranene-dl0 22.91 Hit# Of 5 Tentative ID MW MolForm CAS# Qual 1 Thiocyanic acid, 2-benzothiazoly ... 192 C8H4N2S2 006011-99-0/40 2 4-Hydroxy-3,5-dimethylcinnamic acid 192 C11H1203 1000132-15-8 38 3 2,4-Diamino-6-(hydroxymethyl)pte... 192 C7H8N60 000945-24/4 36 4 3-(2-Methoxy-5-methylphenyl)acry... 192 C11H1203 103986-76-1 33 Abundance Scan 3312 (22.539 min): 11904.D (-3299) (-) m/z 192.10 100.00% 19/2

5000

146 82 160 96 22.20 22.40 22.60 22.80 42 66 nz-> 118 O mmTTTTTNTHTTT 11 “ ■11 ■"11 “ • ■ i •' mm - 20 30 40 50 60 70 80 90 100 110120 130140150 160 170180190 200 m/z 191.00 22.61%

Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 192

5000, 22.20 22.40 22.60 22.80 | m/z 146.10 17.69% 69 108 134 45 90 I 122 I 148 160 0 ’1’1111901111033171111 Jl . J| . . I. ! I ■ . ■ |. , I, ( . I'! , . . . ! I.. 11 . I'l . | . . i 11, ... | . .'I. | . . . . | . 1 . ry '" i ■1 nfa-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81030:4-Hydroxy-3,5-dimethylcinnamic acid 192

22.20 22.40 22.60 22.80 5000 m/z 96.00 13.69% 175 45E 63| 77 89 145 Of ‘i , l 105 117 1111 u I'l1! ’ri rile ’rtltrrr HTnpTPTgH 135 II. 163 , I niz-> 2030405060 70 8090 100 110 120 130 140 150 160 170 180 190 200 Abundance #80958:2,4-Diamino-6-(hydroxymethyl)pteridine ■ ' i ■ ■ ■ ■ i ' ■ i ■ ■ • ■ i ■ ‘ ■ i 43 163 192 22.20 22.40 22.60 22.80 m/z 193.10 10.41 5000 28 53 68 146 176 92 106 121 133

/z—> 0- — ls—yl—pll+ 77 n’t----- - 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80

11904.D 052202.M Tue May 28 12:09:24 2002 Page 17

NYC-WTC_000012958

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