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GCMS analysis results for unknown compounds, June 2002

Machine-extracted title · confidence 90%

Laboratory report documenting GCMS analysis of sample AE12736 with surrogate recovery data and identification of unknown compounds.

NYC-WTC_000015224–000015252

Folder label: “GCMS X 6/3/02 A 6/7/02

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OCR status: ok · source: pdftotext

NYC 9/11 Public Portal Document Library Search Compound Report

Data File C: \MSDCHEM\1\DATA\ 0607 02 \ 12 737.D Vial: 13 Acq On 7 Jun 2002 6:21 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 17 Benzoic acid, 4-ethoxy-, et... Concentration Rank 19 R.T. EstConc Area Relative to ISTD R.T. 19.14 0.26 ug/L 216442 Acenapthalene-dl0 18.52 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzoic acid, 4-ethoxy-, ethyl e... 194 C11H1403 023676-09-7 64 2 Benzoic acid, 4-ethoxy-, ethyl e... 194 C11H1403 023676-09-7/46 3 Propylparaben 180 C10H12O3 000094-13-3 43 4 Ethylparaben;166 C9H10O3 000120-47-8 43 Abundance Scan 2734 (19,143 min): 12737.D (-2727) (-) m/z 121.00 100.00% 121

149 5000

39 65 93 138 166 194 1....... 18,80 19.00 19.20 19.40 0 n..... 111721249.11/7011/11 . ......................... ‘ 1’14 T m/z 149.00 62.43% miz-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #54970: Benzoic acid, 4-ethoxy-, ethyl ester 121

149 5000 - 138 18.80 19.00 19.20 19.40 194 29 _ 93 166 m/z 194.10 39.13% 65

n/z-> 0 15 || 39 Ttptt nmmmm 50 L 1.179... TII’r „| 76 ,| 103 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #121177: Benzoic acid, 4-ethoxy-, ethyl ester 121

149 18.80 19.00 19.20 19.40 5000 194 m/z 138.00 26.25% 65 138 93 166

nfe-> 0+ ., 11 ■ । ।। 50 , ■ I1'' ■ ■ ।1 ■ US,. 111.19%.../ — 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 179 1’00-1’171117 11 ■ ■1 ■ i1 ■ ■ ■ i ■ " i"1

Abundance #121172: Propylparaben I 121 18.80 19.00 19.20 19.40 m/z 65.10 20.64% 138 5000

27 39 93 65 180 I , , 81 |53 109 | , 151 163 | 0 ‘‘1"T-p-tpTTTTTTTTTTTTTTTTT | " " f‘ " U rnri । i , ■, , 11 i >, । i i, 1411//1II11 1 i ■ ■ ' ■ i ■ ■ ■ 1 I ' m/z-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 18.80 19.00 19.20 19.40

12737.D 060302.M Mon Jun 10 11:24:25 2002 Page 20

NYC-WTC_000015248

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NYC-WTC_000015248Source: NYC Law Department, mirrored locally

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