GCMS results sample AE08255, April 2002

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Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\020417\08255.D Vial: 13 Acq On : 17 Apr 2002 7:22 pm Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98.L ********************************************************************* Peak Number 9 Thiocyanic acid, 2-benzothi... Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T.

22.64 0.31 ug/L 485443 Phenanthranene - dl 0 23.02

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 53 2 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 50 3 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 50 4 Bitoscanate 192 C8H4N2S2 004044-65-9 47 Abundance Scan 3330 (22 645 mm) 08255 D (-3320) (-) m/z 192.10 100.00% 192

5000

146 160 22.40 22.60 22 80 23.00

TT/Z-> 0 • i•• i• 20 30 4054 70 2226 .| 40 , 1111,, i HHt+, l-n 1111 >, । 50 118 -H— 11" " i' m i " ; r 1" i 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 — m/z 191.10 19.46% Abundance #80870 Thiocyanic acid, 2-benzothiazolyl ester 19 2

5000 22.40 22 60 22 80 23 00 m/z 146.10 15.85% 45 . 7 82 90 108 122 ’I4 148 160 0 ............. . ----- ‘ l...... ‘I’’ n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125842 Phenanthrene, 2-methyl- 1912

2240 22.60 22.80 23.00 5000 m/z 193.00 13.43%

96 27 39 51 63 74 82 ,|| 115 126 139 152 165 '176 01 ' i1 " ' r ■ ■1 r ’11111 ■ ■ r '''1 r 11 ■ i '1’ ■ **mH ■ ■ i ■ ■ n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033 Phenanthrene, 9-methyl- 192 22.40 22.60 22.80 23 00 m/z 96.10 10.59% 5000

96 165 । । 29 39 51 63 75 83 1 115 126 139 152 j 176 0 IUBa—nIIUBTIPTTT—r 1-—+ " I ■1 /z- > 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.40 22 60 22.80 23.00

08255.D 041702SCAN.M Thu Apr 18 09:24:59 2002 Page 13

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