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GCMS analysis results for sample AE10811, May 2002

Machine-extracted title · confidence 50%

Gas chromatography-mass spectrometry report for sample AE10811 showing detection of unknown compounds and surrogate recovery.

NYC-WTC_000046036–000046063

Folder label: “GCMS X 5/7/02 A 5/15/02

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NYC 9/11 Public Portal Document

- Data File : C:\MSDCHEM\1\DATA\051402\10811.D Vial: 21 Acq On : 15 May 2002 6:39 am Operator: Mclean Sample : 5/7 kb Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98 . L

Peak Number 14 Phenanthrene, 9-methyl- Concentration Rank 14

R.T. EstConc Area Relative to ISTD R.T.

22.58 0.30 ug/L 394160 Phenanthranene-dl0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 59 2 2-Propenal, 3-(3,4-dimethoxyphen.. . 192 C11H12O3 004497-40-9 42 3 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 40 4 2,4-Diamino-6-(hydroxymethyl)pte... 192 C7H8N6O 000945-24-4 38 Abundance Scan 3319 (22,580 min): 10811.D (-3310) (-) m/z 192.10 100.00% 192

5000

.................. /............./ t | i” r ' i l > । I | i > I I | I "T I "I I ■ I"

96 42 70 82 | 120 146 160 II 22.20 22.40 22.60 22.80 23.00 0 IT Pii I | ( I I I | I I I I j I I 1 1 | T I I I | I I I I | I 1 I ithe......... II,..,,,, ----- m/z 191.10 16.57% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033: Phenanthrene, 9-methyl- 192

— 5000 22.20 22.40 22.60 22.80 23.00 m/z 146.20 13.51% 96 29 39 51 63 74 83 j 0 ———p—nmp—010010’—2—TTTTTT 115,126139.152.147,1764 '‘r 1 m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80953: 2-Propenal, 3-(3,4-dimethoxyphenyl)- 192 161 ) 22.20 22.40 22.60 22.80 23.00 5000 m/ z 193.10 12.45%

52 52 64 77- 91 103 121 138 149 177

m/z-> 0 1 I 1 ' " I " " I " " P1" 1 | ''I । । | n JI | , M Y 20 30 40 50 60 70 80 90 100 110 120J 30 140 150 160 170 180 190 200 -HH l Abundance #125842: Phenanthrene, 2-methyl- 192 22.20 22.40 22.60 22.80 23.00 m/z 96.00 12.40%

5000

96 27 39 51 63 82 II 115 126 139 152 165 176 L 0 1 r 1 ■' r ' "'1111' P 1111'''11 r '''1 T* C’0’e’2-’I’dddp’***a**ddI**ddSbdd i’H ’atallguni T-p-r ' I ' ' 1 1 I 1 1 1 1 1 1 ' ' 1 1 1 /z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

10811.D 050102.M Thu May 16 14:13:28 2002 Page 18

NYC-WTC_000046058

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NYC-WTC_000046058Source: NYC Law Department, mirrored locally

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