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GCMS analysis results for sample AE10810, May 2002

Machine-extracted title · confidence 50%

Gas chromatography-mass spectrometry report for sample AE10810 showing detection of unknown compounds and surrogate recovery.

NYC-WTC_000046006–000046035

Folder label: “GCMS X 5/7/02 A 5/15/02

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NYC 9/11 Public Portal Document

'Data File : C:\MSDCHEM\1\DATA\051402\10810.D Vial: 20 Acq On : 15 May 2002 5:50 am Operator: Mclean Sample : 5/7 kb Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98.L ********************************************************************* Peak Number 6 Phenanthrene, 9-methyl- Concentration Rank 15

R.T. EstConc Area Relative to ISTD R.T.

22.58 0.32 ug/L 412416 Phenanthranene-dl0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 59 2 Phenanthrene, 1-methyl- 192 C15H12 000832-69-9 59 3 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 59 4 2,4-Diamino-6-(hydroxymethyl)pte... 192 C7H8N60 000945-24-4 45 Abundance Scan 3318 (22.574 min): 10810.D (-3311) (-) m/z 192.10 100.00% 192 A

5000 ........ . 92 96 40 54 66 । | 118 . ....................................... |....... 146 160 11 22.20 22.40 22.60 22.80 23.00 0 TITTPT — I I I 1 I I I I I > I ' I I I I I I I I I I I I I I I I I ■ I I I m/z 191.00 16.34% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033: Phenanthrene, 9-methyl- 192

.............. ......................................... 5000 22.20 22.40 22.60 22.80 23.00 m/z 146.10 14.04% 96 165 i 29 39 51 63 74 83 J 115 126 139 152 j 176 I 0 ’i 111111! 111 ]t 11! i'!!! 11 ts!! ।..... i'I'i . 11. ri. । > 11 > । < > i. ।. 11. । > < > . |. 11 > 11... । UTTT— < 1111 -11 | I— m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125856: Phenanthrene, 1-methyl- 192 ...... 0 22.20 22.40 22.60 22.80 23.00 5000 m/z 193.10 13.47%

96

m/z-> 0 27 39 51 63 । i > i . । rn i । i i i > p > . rp'. < r| 20 30 40 50 82. 115 126 139 152 165 178 TT 11 " 111........ 11111 |'i 11111'ri 1111 li| 11 i’Ii 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 , Tur Abundance #125842: Phenanthrene, 2-methyl- ■' I ' 1 1 "Itir ‘‘11‘1‘I* 192 22.20 22.40 22.60 22.80 23.00 m/z 96.10 13.28%

5000

m/z-> 0 27 39 51 63 ■ । ■ i < i | r 1 i i । > i i i | i i i i | i I i i | 82 96 1 115 126 139 152 E 190 176 Tr "I 1/uuul 15*** , । , , , . । , 1‘p ‘11! m | ir , TTTTT 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 u -

22.20 22.40 22.60 22.80 23.00

10810.D 050102.M Thu May 16 12:39:31 2002 Page 10

NYC-WTC_000046020

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NYC-WTC_000046020Source: NYC Law Department, mirrored locally

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