GCMS analysis results for sample AE09330, May 8 2002

NYC 9/11 Public Portal Document

’Data File C:\MSDCHEM\1\DATA\050202\9330.D Vial: 10 Acq On 2 May 2002 6:58 pm Operator: Mclean Sample 4/29 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 5 Phenanthrene, 9-methyl- Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

22.58 0.40 ug/L 540244 Phenanthranene-dl0 22.96

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 59 ? 2 Phenanthrene, l-methyl- 192 C15H12 000832-69-9 42 3 Isoquinoline, 1,2,3,4-tetrahydro... 328 C18H20N2O4 1000128-79-2 42 4 (-)-1,2,3,4-Tetrahydroisoquinoli... 251 C13H17NO4 1000127-91-1 42 Abundance Scan 3319 (22.580 min): 9330.D (-3311) (-) m/ z 192.10 100.00% 192

5000

96 146-160 1 1 1 1 1 1 T1 1 22.20 22.40 22.60 22.80 23.00 .. A 1 ' I ' 1 1 - I 1

42 118 | | ,1, /z-> II’1 .... 79.4 1111' 111111 ITr11 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 m/z 191.10 18.80% Abundance #81033: Phenanthrene, 9-methyl- 192

5000 ..... n... / 22.20 22.40 22.60 22.80 23.00 m/z 193.10 17.47% 96 165 । 39 63 81 , 115 139......... ........ ........... . pi I I I [ I l"l I | I I I "I | I I I I I I I 1 | I 1 । । | I I I I | T i i t | i O |-| I r i I । i i . i । | i . | । . r i i | i I I i । । i i i | . ■ I i ।

m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #125856: Phenanthrene, 1-methyl- 192 ...... n..... a 22.20 22.40 22.60 22.80 23.00 5000 m/z 146.10 13.19%

96 PE 39 i ' ■ '1 i1 1 +63.814115139. 1 i1 ■'11 I1 ’11 1 t ■ । ■ i ■ ■ ■ ■ । । • i n/z—> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #81065: Isoquinoline, 1,2,3,4-tetrahydro-1-[2-nitrobenzyl]... .................. 1 I I I A............. I I I I II II I I I / I 1 I I I I 'I 192 22.20 22.40 22.60 22.80 23.00 m/z96.00 12.89%

5000

176 49 63 78 92 11/131 148162 | 207222236250264 280 295 311 328 "J I I I I । । i' I I | l‘ | I l" । I i' I I | I i । I | rili I’ ’ । । । j 'll 11 1 I “rpri-iT । i i । । । । । । i । । । । । | I i i i । i i i r | i i i । । 1 I I I bit | I I I I [ I ' I I I I I t 1 I I

/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 22.20 22.40 22.60 22.80 23.00

9330.D 050102.M Mon May 06 13:55:11 2002 Page 8

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