GCMS calibration results for method 508, May 6 2002

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Data File C:\MSDCHEM\l\DATA\050202\CAL50CC.D Vial: 29 Acq On 3 May 2002 12:09 pm Operator: Mclean Sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: May 06 12:27:57 2002 Quant Results File: 050102.RES

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Last Update : Mon May 06 12:20:41 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.94 152 3771942 40.00 ug/L 0.00 10) Napthalene-d8 13.44 136 15423260 40.00 ug/L 0.00 17) Acenapthalene-dlO 18.58 164 8272843 40.00 ug/L 0.00 29) Phenanthranene-dlO 22.96 188 12274176 40.00 ug/L 0.00 37) Chrysene-dl2 30.83 240 8798382 40.00 ug/L 0.02 43) Perylene-dl2 34.72 264 6683266 40.00 ug/L 0.00

System Monitoring Compounds 2 7) TCMX 20.55 209 612536 10.54 ug/L 0.00 Spiked Amount 10.000 Recovery = 105.40% 50) 2,4-ddd 0.00 235 0 0.00 ug/L Spiked Amount 5.000 Recovery = 0.00%

Target Compounds 2) n-nitros-dimethyl amine 3.84 74 35-75 Qvalue 4232977 54.77 ug/L 89 3) bis(2-Chloroethyl)ether 9.36 93 7592590 51.45 ug/L 89 4). 1,3-Dichlorobenzene 9.77 146 7185578 47.83 ug/L 98 5) 1,4-Dichlorobenzene 9.99 146 7732872 50.06 ug/L 99 6) 1,2-Dichlorobenzene 10.36 146 6934636 50.49 ug/1 99 7) 2,2'oxybis(1-Chloropropane 10.81 45 11767440m 51.73 ug/L 8) N-nitroso-di-propylamine 11.15 70 5366004 51.29 ug/L 97 9) Hexachloroethane 11.26 117 2944830 51.69 ug/L 92 11) Nitrobenzene 11.51 77 7674633 51.44 ug/L 96 12) Isophorone 12.22 82 13723371 51.06 ug/L 99 13) bis(2-Chloroethoxy) methan 12.96 93 9082529 51.01 ug/L 99 14) 1,2,4-Trichlorobenzene 13.31 180 5692569 50.37 ug/L 98 15) Napthalene 13.50 128 20276483 49.07 ug/L 99 16) Hexachlorobutadiene 13.94 225 2678845 50.60 ug/L 99 18) 2-Chloronaphthalene 16.94 162 10621020 50.34 ug/L 99 19) Dimethylphthalate 18.03 163 13691116 50.63 ug/L 100 20) 2,6-Dinitrotoluene 18.14 165 2343655 55.14 ug/L 90 21) Acenapthylene 18.14 152 17938539 45.98 ug/L 98 22) Acenapthalene 18.67 153 11090195 49.30 ug/L 97 23) 2,4-Dinitrotoluene 19.29 165 3169594 52.69 ug/L 97 24) Diethylphthalate 20.16 149 12082942 51.39 ug/L 98 25) 4-Chlorophenyl-phenylether 20.34 204 6214734 50.01 ug/L 98 26) Fluorene 20.21 166 12969187 50.40 ug/L 97 28) Azobenzene 20.80 77 15736641 50.71 ug/L # 94 30) Nnitrosodiphenylamine 20.71 169 7352207 48.81 ug/L 95 31) 4-Bromophenyl-phenylether 21.77 248 3119615 51.46 ug/L 99 32) Hexachlorobenzene 21.81 284 2889593 49.79 ug/L 98 33) Phenanthrene 23.03 178 18077061 48.82 ug/L 97

(#) = qualifier out of range (m) = manual integration CAL50CC.D 050102.M Mon May 06 12:29:17 2002 Page 1

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