GCMS calibration results for deuterated standards, May 2 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C : \MSDCHEM\1\DATA\050102\CAL50 .D Vial: 5 Acq On 1 May 2002 12 : 57 pm Operator: Mclean Sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: May 02 09:41:47 2002, Quant Results File: 050102.RES

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Last Update : Thu May 02 09:38:23 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.94 152 4903374 40.00 ug/L 0.00 10) Napthalene-d8 13.44 136 19883307 40.00 ug/L 0.00 17) Acenapthalene-dlO 18.58 164 10558508 40.00 ug/L 0.00 29) Phenanthranene-dlO 22.96 188 15873554 40.00 ug/L 0.00 37) Chrysene-dl2 30.84 240 11329913 40.00 ug/L -0.03 43) Perylene-dl2 34.72 264 8291257 40.00 ug/L -0.02

System Monitoring Compounds 2 7) TCMX 20.55 207 855335 10.26 ug/L -0.01 Spiked Amount 10.000 Recovery 02.60%

Target Compounds 51 Qvalue 2) n-nitros-dimethyl amine 3.86 74 5846275 60.76 ug/L 92 3) bis(2-Chloroethyl)ether 9.36 93 9876011 51.48 ug/L 88 4) 1,3-Dichlorobenzene 9.78 146 9224722 49.83 ug/L 99 5) 1,4-Dichlorobenzene 9.99 146 9900606 49.27 ug/L 99 6) 1,2-Dichlorobenzene 10.36 146 8911755 49.89 ug/1 99 7) 2,2'oxybis(1-Chloropropane 10.81 45 15305291m 51.68 ug/L 8) N-nitroso-di-propylamine 11.16 70 7113621 52.27 ug/L 96 9) Hexachloroethane 11.27 117 3797673 51.25 ug/L 95 11) Nitrobenzene 11.51 77 10234602 53.19 ug/L 95 12) Isophorone 12.22 82 17883171 51.60 ug/L 99 13) bis(2-Chloroethoxy) methan 12.96 93 11773153 51.33 ug/L 99 14) 1,2,4-Trichlorobenzene 13.31 180 7258874 49.82 ug/L 99 15) Napthalene 13.50 128 26084579 48.97 ug/L 99 16) Hexachlorobutadiene 13.94 225 3371484 49.40 ug/L 99 18) 2-Chloronaphthalene 16.94 162 13519880 50.15 ugIL 99 19) Dimethylphthalate 18.03 163 17874887 51.73 ug/L 100 20) 2,6-Dinitrotoluene 18.15 165 3129038 57.63 ug/L 90 21) Acenapthylene 18.14 152 22654328 48.23 ug/L 99 22) Acenapthalene 18.68 153 14033381 48.81 ug/L 98 23) 2,4-Dinitrotoluene 19.30 165 4495074 58.55 ug/L 96 24) Diethylphthalate 20.17 149 15634899 52.04 ug/L 99 25) 4-Chlorophenyl-phenylether 20.35 204 7960503 50.13 ug/L 98 26) Fluorene 20.22 166 16379232 49.84 ug/L 98 28) Azobenzene 20.80 77 20317403 51.25 ug/L # 93 30) Nnitrosodiphenylamine 20.71 169 8752293 45.00 ug/L 94 31) 4-Bromophenyl-phenylether 21.78 248 3866623 49.32 ug/L 96 32) Hexachlorobenzene 21.81 284 3614667 48.16 ug/L 98 33) Phenanthrene 23.04 178 23127184 48.31 ug/L 98 34) Anthracene 23.19 178 24234147 49.47 ug/L 98 35) Di-n-butylphthalate 25.11 149 27839308 52.95 ug/L 100

(#) = qualifier out of range (m) = manual integration CAL50.D 050102.M Thu May 02 09:42:37 2002 Page 1

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