GCMS calibration results for deuterated standards, May 2 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\1\DATA\0 5 010 2\CAL8 0.D Vial: 6 Acq On 1 May 2002 1:46 pm Operator: Mclean Sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: May 02 09:40:47 2002 Quant Results File: 050102.RES

Quant Method C:\MSDCHEM\l\METHQDS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Last Update Thu May 02 09:38:23 2002 Response via Initial Calibration DataAcq Meth 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.94 152 4314752 40.00 ug/L 0.00 10) Napthalene-d8 13.44 136 17607099 40.00 ug/L 0.00 17) Acenapthalene-dlO 18.58 164 9401597 40.00 ug/L 0.00 29) Phenanthranene-dlO 22.96 188 13965502 40.00 ug/L 0.00 37) Chrysene-dl2 30.84 240 9404245 40.00 ug/L -0.02 43) Perylene-dl2 34.73 264 7687249 40.00 ug/L -0.02

System Monitoring Compounds 2 7) TCMX 20.55 207 742866 10.01 ug/L 0.00 Spiked Amount 10.000 Recovery = 100.10%

Target Compounds 2) n-nitros-dimethyl amine 3.85 74 7878913 50% 93.05 ug/L Qvalue 90 3) bis(2-Chloroethyl)ether 9.36 93 12879895 76.30 ug/L 88 4) 1,3-Dichlorobenzene 9.78 146 11761471 72.20 ug/L 100 5) 1,4-Dichlorobenzene 9.99 146 12550825 70.99 ug/L 99 6) 1,2-Dichlorobenzene 10.37 146 11405638 72.56 ug/1 99 7) 2,2'oxybis(1-Chloropropane 10.82 45 20310852m 77.94 ug/L 8) N-nitroso-di-propylamine 11.16 70 9293450 77.60 ug/L 95 9) Hexachloroethane 11.27 117 4920476 75.46 ug/L 95 11) Nitrobenzene 11.52 77 13533488 79.43 ug/L 94 12) Isophorone 12.23 82 23124351 75.35 ug/L 98 13) bis(2-Chloroethoxy) methan 12.97 93 15371632 75.69 ug/L 99 14) 1,2,4-Trichlorobenzene 13.32 180 9297036 72.06 ug/L 99 15) Napthalene 13.51 128 32964203 69.89 ug/L 99 16) Hexachlorobutadiene 13.94 225 4268678 70.63 ug/L 99 18) 2-Chloronaphthalene 16.95 162 17426710 72.60 ug/L 100 19) Dimethylphthalate 18.04 163 23239166 75.53 ug/L 100 20) 2,6-Dinitrotoluene 18.16 165 4076431 84.32 ug/L 94 21) Acenapthylene 18.15 152 28299084 67.66 ug/L 99 22) Acenapthalene 18.68 153 17659077 68.98 ug/L 98 23) 2,4-Dinitrotoluene 19.30 165 6094954 89.16 ug/L 96 24) Diethylphthalate 20.17 149 19768893 73.90 ug/L 98 25) 4-Chlorophenyl-phenylether 20.35 204 10167720 71.90 ug/L 98 26) Fluorene 20.22 166 20776143 71.00 ug/L 98 28) Azobenzene 20.81 77 26059824 73.82 ug/L # 92 30) Nnitrosodiphenylamine 20.72 169 10997524 64.26 ug/L 95 31) 4-Bromophenyl-phenylether 21.78 248 4905238 71.11 ug/L 97 32) Hexachlorobenzene 21.82 284 4647993 70.39 ug/L 100 33) Phenanthrene 23.04 178 29030435 68.93 ug/L 98 34) Anthracene 23.20 178 30205282 70.08 ug/L 99 35) Di-n-butylphthalate 25.11 149 35121959 75.93 ug/L 100

(#) = qualifier out of range (m) = manual integration CAL80.D 050102.M Thu May 02 09:41:39 2002 Page 1

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