GCMS calibration results for volatile organics, May 2002

NYC 9/11 Public Portal Document

* Data File C:\MSDCHEM\1\DATA\0 513 0 2\CALS 0.D Vial: 3 Acq On 13 May 2002 11:39 am Operator: Mclean Sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: May 13 12:20:23 2002 Quant Results File: 050102.RES

Quant Method : C:\MSDCHEM\l\METHQDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Last Update : Mon May 13 12:18:47 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.94 152 5334168 40.00 ug/L 0.00 10) Napthalene-d8 13.43 136 21524835 40.00 ug/L 0.00 17) Acenapthalene-dlO 18.57 164 11618554 40.00 ug/L 0.00 29) Phenanthranene-dlO 22.95 188 17060140 40.00 ug/L 0.00 37) Chrysene-dl2 30.82 240 11863071 40.00 ug/L 0.01 43) Perylene-dl2 34.71 264 8264555 40.00 ug/L 0.00

System Monitoring Compounds 27) TCMX 20.54 209 861450 12.21 ug/L 0.00 Spiked Amount 10.000 Recovery = 122.10%

Target Compounds 55 65 Qvalue 2) n-nitros-dimethyl amine 3.83 74 5666336 51.84 ug/L # 86 3) bis(2-Chloroethyl)ether 9.35 93 10422461 49.94 ug/L 89 4) 1,3-Dichlorobenzene 9.77 146 10127311 47.66 ug/L 99 5) 1,4-Dichlorobenzene 9.98 146 10970603 50.22 ug/L 99 6) 1,2-Dichlorobenzene 10.36 146 9750692 50.20 ug/1 99 7) 2,2'oxybis(1-Chloropropane 10.81 45 16666130m 51.81 ug/L 8) N-nitroso-di-propylamine 11.15 70 7443886 50.31 ug/L 97 9) Hexachloroethane 11.26 117 4173248 51.80 ug/L 93 11) Nitrobenzene 11.50 77 10611366 50.96 ug/L 95 12) Isophorone 12.21 82 19075291 50.85 ug/L 99 13) bis(2-Chloroethoxy) methan 12.95 93 12491121 50.26 ug/L 98 14) 1,2,4-Trichlorobenzene 13.31 180 7989558 50.66 ug/L 98 15) Napthalene 13.50 128 28388000 49.23 ug/L 99 16) Hexachlorobutadiene 13.93 225 3814895 . 51.63 ug/L 98 18) 2-Chloronaphthalene 16.94 162 14906542 50.31 ug/L 98 19) Dimethylphthalate 18.02 163 18940006 49.87 ug/L 99 20) 2,6-Dinitrotoluene 18.13 165 3219864 53.94 ug/L 91 21) Acenapthylene 18.13 152 25253451 46.09 ug/L 98 22) Acenapthalene 18.67 153 15656031 49.55 ug/L 98 23) 2,4-Dinitrotoluene 19.29 165 4263327 50.47 ug/L 96 24) Diethylphthalate 20.15 149 16818850 50.94 ug/L 98 25) 4-Chlorophenyl-phenylether 20.34 204 8837885 50.63 ug/L 98 26) Fluorene 20.21 166 18175573 50.29 ug/L 99 28) Azobenzene 20.79 77 21690512 49.77 ug/L # 93 30) Nnitrosodiphenylamine 20.70 169 10374892 49.55 ug/L 93 31) 4-Bromophenyl-phenylether 21.77 248 4427833 52.54 ug/L 97 32) Hexachlorobenzene 21.80 284 4195349 52.01 ug/L 100 33) Phenanthrene 23.03 178 25424220 49.40 ug/L 98 34) Anthracene 23.18 178 26274624 49.91 ug/L 98 35) Di-n-butylphthalate 25.10 149 28996556 51.31 ug/L 100

(#) = qualifier out of range (m) = manual integration CAL50.D 050102.M Tue May 14 11:49:44 2002 Page 1

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