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GCMS analysis results for sample AE10705, May 20 2002

Machine-extracted title · confidence 100%

Gas chromatography-mass spectrometry report for sample AE10705 showing detection of unknown compounds and surrogate recovery.

NYC-WTC_000045811–000045823

Folder label: “GCMS X 5/3/02 A 5/13/02

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NYC 9/11 Public Portal Document

’Data File : C:\MSDCHEM\1\DATA\020513\10705.D Vial: 16 Acq On : 14 May 2002 3:23 am Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020507.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1

Peak Number 5 Anthracene-dlO- Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T. 31.96 0.38 ug/1 46394 Phenanthrene-dl0 31.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

" 1 Anthracene-dlO- 188 C14D10 001719-06-8 59 2 Pheranthrene-d10 188 C14D10 001517-22-2 59 3 Benzene, 1-bromo-4-methoxy- 186 C7H7BrO 000104-92-7 47 4 1,4-Naphthalenedione, 2-hydroxy-... 188 C11H8O3 000483-55-6 28 Abundance Scan 4915 (31.958 min): 10705.D (-4908) (-) m/z 188.15 100.00% its

5000

80 94 TT -OOBB/TTFT""LT 110 144 156 31.60 31.80 32.00 32.20 - 44 54 ee 1 ‘ 1 I " " I " " I " " I 1 L-r|-!-i L ( 1 i THM 176 m/z 189.20 25.07% m/z-> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 Abundance #79826: Anthracene-d10- 188

5000 m 31.60 31.80 32.00 32.20 m/ z 184.15 22.12% 80 94 160 । 17 30 42 52 ° I 108 118 132 146 | 170179 | 1 1 1 1 । । । । ' । > । । । । I । । । । I I । 1 । rl I i । i i I I | i । i 11 I I । । TTTTTII ri । t i i i [ I ri i | i i li । i t l*ll|*i r r i | i i i i | I'Pl T’uty m/z—> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188

31.60 31.80 32.00 32.20 5000 m/z 187.10 18.67%

80 94 160 42 52 ■ t■66 30 108118 132 146 nJ 170179,|,| | 11> I"111" " 111-1 p TTT 111 ■1" r " 1111" 11" ' i111 ‘TM1 | I 1 I I p I I I | I I Fr rT"T u I | I I I ! | I’TTi I I I ‘I m/z-> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 Abundance #79820: Benzene, 1 -bromo-4-methoxy- ' i 11 1 1 I 1 1 1 1 I ' 1 1 1 I 1 1 1 1 I 1 188 31.60 31.80 32.00 32.20 m/z 94.10 18.06% 63 143 173 5000 50 77 38 92 15 29 1. , w..l. . .. I'. 107117..... 4 ...... ...... 111' ■1 11 1111A 155 " I" " 11' "I" " I' " 111 h ri111 I'1" I > l > ■ • V-] . . .-r । i t ' ' i । < । । । ■ n/z-> 10 20 30 40 50 60 70 80 90 100 110120 130 140 150 160 170 180 190 31.60 31.80 32.00 32.20

10705.D SCAN020507.M Wed May 15 09:03:23 2002 Page 7

NYC-WTC_000045821

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