GCMS calibration data for method 508, April 23 2002

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Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\APR2 202\8757.D Vial: 13 Acq On : 22 Apr 2002 8:55 pm Operator: Sample : gc/ms scan 4/11 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 17 Coprostan-3-one Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

40.43 3.18 ug/1 346530 Perylene-dl2 37.87

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Coprostan-3 -one 386 C27H46O 000000-00-0 70 2 Cholesterol 386 C27H46O 000057-88-5 38 3 Pregnane-3,20-dione, (5.beta.)- 316 C21H3202 000128-23-4 35 4 Chol.estan-1-one________________ 386 C27H460 055700-37-3 25 Abundance Scan 3855 (40.434 min): 8757.D (-) m/z 231.10 100.00% 56 81 231 386 .1 107 161 316 5000- 133 213 189 353 255 275 40.20 40.40 40.60 40.80 Jj — rI I 1 IJ MH 111’I 01111111111111111111111117111111077 m/z 55.00 96.50%

X m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 Abundance #52763: Coprostan-3-one 43

5000 231 386 40.20 40.40 40.60 40.80 67 95 m/ Z 43.00 90.85% W 11 123 161 316 lh... I ... TT r'11111 " 1 r 111 r 11 L 1 i1 ■ ■ ■ i11111'1' ’ i1 ■'' I 111111 I 368 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 Abundance #74135: Cholesterol 43 i ■ ■ 40.20 40.40 40.60 40.80 149 386 83.40% 107 m/ Z 81.00 5000- / 275 . 213 301 , 255 353 ........ I................ I ' l1" 1111 " l r' ‘ • I.% 111.1.. I " 11111. < I > > > 11111 > r . > > 11.1I > It.................... askks/ak ■ I | 1 I I I | 1 i i i | r i i i | >

m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 Abundance #45159: Pregnane-3,20-dione, (5.beta.)- W AN, . WMX, 43 40.20 40.40 40.60 40.80 m/z 386.30 82.22%

5000- 84 246 107 298 316 135 159176 213 ...... | 272 r r । i i i i । i ■ Pi i । । । । । । । । । ।. ..... । । । nI i ni pi । । I I I I ( I [ I I I I I I I I 1*1 I I I I I I I l fin i1" 1 r 11' 11" ' r 1 _ A , , ... . ■ । । i i 'i । । i । । । । । । । । i r

m/z—> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 40.20 40.40 40.60 40.80

8757.D GCMS0412.M Tue Apr 23 08:23:10 2002 Page 17

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