GCMS calibration data for method 508, April 23 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\l\DATA\APR2202\8757.D Vial: 13 Acq On : 22 Apr 2002 8:55 pm Operator: Sample : gc/ms scan 4/11 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 13 Carbazole Concentration Rank 12 R.T. EstConc Area Relative to ISTD R.T. 26.31 0.29 ug/1 54986 Phenanthrene-dl0 25.59 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Carbazole 167 C12H9N 000086-74-8 (94 2 D-Galactitol, 2-(acetylmethylamino) 363 C16H29NO8 074410-42-7 91 3 9H-Carbazole, 9-nitroso- 196 C12H8N2O 002788-23-0 58 4 N-Hydroxymethylcarbazole 197 C13H11NO 000000-00-0 43 Abundance Scan 2317 (26.314 min): 8757.D (-) m/z 167.00 100.00% 167

5000

139 26.00 26.20 26.40 26.60 39 55 69 83 11 'l' <“ 44*# 113 _ 4 i188 111 1 11 r r 1 ''' i ■ ■ ■ ■ 11' 111 ■ ''' r 11' i' ''11' 1 m/z 166.10 21.51% m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #68050: Carbazole 167

5000 1 1 i ' ■ 1 ' i ■ 1 ■ 1 i 1 ' 1 1 i 1 1 1 1 i 26.00 26.20 26.40 26.60 m/z 168.00 15.25% 139 ''I''''I' m/z->_____ 40 60 89 T-j-n-r i । rt ।113—+। । । । । । । RP-mn"nni, । 80 '100 120 140 160 180 200 220 240 260 _ 280 300 320 340 Abundance #50626: D-Galactitol, 2-(acetylmethylamino)-2-deoxy-3,4,6-t 167 l-l-1” l-1-l

26.00 26.20 26.40 26.60 5000 m/z 139.05 12.03%

83 . 139 327 343 0- ....... . ................................ . ..... 1 ■ i1111 r 1 1 r i1 ■ ■111''1 r 111111 ■ ■ i ■ ■1111 1 i i | i i i । | i i i । | I T i r | i I ii | i i i i | I 1 । 1 | II II I I

m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #69471: 9H-Carbazole, 9-nitroso- ‘ ' i ■ ■ ' 1 i 1 1 1 1 i 1 1 ■ ' i ■ ' ■ 1 i 167 26.00 26.20 26.40 26.60 m/ z 83.45 10.32% / 5000

83 139

m/z-> .............. .......... ................ .......................................................... । । । । । ' । । । । । । । । । । । । । । । । ( । । । । । > । । । । । । । i । । । । । । । । । । । । । । । | । । i । | i I i । | i । i i| i i i i । r f i i । i r i

40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 | NWA NNArMAMMwA II I I I I I I I I ""UN I I I I I I I I

26.00 26.20 26.40 26.60

8757.D GCMS0412.M Tue Apr 23 08:23:06 2002 Page 13

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