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GCMS calibration table for TCLP method, Dec 2001

Machine-extracted title · confidence 100%

Quality reviewed GCMS calibration data listing surrogate compounds and retention times from December 14, 2001.

NYC-WTC_000036729–000036751

Folder label: “GCMS X 12/7/01 A 1/2/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : M:\INSTRU~1\2O9\DATA\DEC13O1\29522.D Vial: 21 Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title 209 625/TCLP calibration table Library C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 16 Nicodicodine Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

38.18 64.30 ug/1 18777400 Perylene-dl2 37.10

Hit# of 5 ntative ID MW MolForm CAS# Qual

1 Nicodicodine 406 C24H26N2O4 000808-24-2 10 2 3,3',8,8-Tetrahydroxy-6,61-dimethy 406 C22H1408 088381-85-5 9 3 5-(4-An(yloxyphenyl )-2- (4-butoxy-2-h 406 C25H30N2O3 000000-00-0 9 4 2-(2 -/lydr oxy-4 - nonyl oxyphenyl)-5-(4 406 C25H30N2O3 000000-00-0 9 'Abundance Scan 3610 (38.183 min): 29522.D (-) m/z 104.95 100.00% 105 391

5000

77 301

m/z-> 54125.112.172,202,,133s252259, I ( 327 359 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 tlp। A।1T1.। t i i i । n ik । 4)8 TTTT 37.80 38.00 38.20 38.40 38.60 m/z 391. 77.32% Abundance #54406: Nicodicodine 406

... 5000 • i ' ■ ' ■ । ' IT 37.80 38.00 38.20 38.40 38.60 284 m/z 406.20 50.39% 78 106

1 59 j | TTTTTTTT TTTTTTTTT TT 193 226 248 J 301 ' 111111'' r I.... 1... 111 > 1111> > T‘‘I i" " i pn 1 350 m/z—> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 . 'Abundance #5*1383: 3,3‘,8.8‘-Tetrahydroxy-6,6‘-dimethyl-2,2‘-binaphtha 406 i1 37.80 38.00 38.20 38.40 1 ■ i ’ 38.60 5000 - 350 m/z 392 24.86% 135 84 333 378. j I II IjH.i | I I I I | I I « I | I . I . | . .1 n .1. 1 (" " I 1'1119'71111 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 Abundance #54415: 5-(4-Amyloxyphenyl)-2-(4-butoxy-2-hydroxyphenyl)pyr 406 37.80 38.00 38'20 38.40 38.60 m/ z 21.55% 5000 - 280 350 118 89 223 251 322 , 376 i , r ।।" i DT I ‘11' 11" ' I " " I TT TTT TTTTTTT 1TTTT " I" " i" " i' ‘IT m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 37.80 38.00 38.20 38.40 38.60

29522.D GCMS1126.M Tue Jan 08 10:55:08 2002 Page 16

NYC-WTC_000036749

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NYC-WTC_000036749Source: NYC Law Department, mirrored locally

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